Äîêóìåíò âçÿò èç êýøà ïîèñêîâîé ìàøèíû. Àäðåñ îðèãèíàëüíîãî äîêóìåíòà : http://www.chem.msu.ru/rus/theses/2014-03-11-nikolajev/abstract.pdf Äàòà èçìåíåíèÿ: Tue Mar 11 22:25:55 2014 Äàòà èíäåêñèðîâàíèÿ: Sun Apr 10 11:12:21 2016 Êîäèðîâêà: Ïîèñêîâûå ñëîâà: jupiter

V ­ VI 02.00.01 ­



­ 2014


..

:

,

:

, «» ,

:

« . .. »

«16» 2014 16 30 501.001.51 .. : 119991, , -1, , 1, 3, , . 446. .. http://www.chem.msu.su. http://vak.ed.gov.ru. «16» 2014 . 501.001.51,
2




. 13 650 ­ 1100 0. [1]. , . - , - , ­ . , : 1) ; 2) ( 1357 ­ 1503 ; 3) ( 1033 ­ 1375 ) [1]. , , , . V ­ VI . . ,
Ni



,







, .

­ , V-VI , -Ni3(Nb,Ta),
3


Ni-Re-Nb-Cr-Mo . : 1. 2. 1375 : Ni-Re-V-Nb; Ni-Re-V-Ta; Ni-Re-Nb-Ta; Ni-Re-Cr-Nb; Ni-Re-Mo-Nb; Ni-Re-W-Nb; Ni-Re-Cr-Ta; Ni-Re-Mo-Ta; Ni-Re-W-Ta. Ni-Re-Nb-Cr-Mo 1375 1200 . 3. 1375 1200 Ni-Re-Nb-Cr-Mo. 4. , , - . : - 1375 : Ni-Re-V-Nb; Ni-Re-V-Ta; Ni-Re-Nb-Ta; Ni-Re-Cr-Nb; Ni-Re-Mo-Nb; Ni-Re-W-Nb; Ni-Re-Cr-Ta; Ni-Re-Mo-Ta; Ni-Re-W-Ta ; , Ni-Re-Nb-Cr-Mo 1375 1200 ; 1375 1200
4


- Ni-Re-Nb-Cr-Mo 1375 1200 , Ni-Re-Cr-Nb, Ni-Re-Mo-Nb, Ni-Re-Cr-Mo, Ni-Nb-Cr-Mo , ; Ni-Re-Nb-Cr-Mo, ; -- Ni-Re-Nb, Ni-Re-Cr, Ni-Re-Mo, Ni-Nb-Cr, Ni-Nb-Mo, Ni-Cr-Mo; 1200 - Ni-Re-Nb-Cr-Mo. , VVI . , . , ( 13-03-00977 « »). , : 1. 1375 : Ni-Re-V-Nb, Ni-Re-V-Ta, Ni-Re-Nb-Ta, Ni-Re-Cr-Nb, Ni-Re-Mo-Nb, Ni-Re-W-Nb, Ni-Re-Cr-Ta, Ni-Re-Mo-Ta, Ni-Re-W-Ta;
5


2. 3.

Ni-Re-Nb-Cr-Mo 1375 1200 ; 1375 1200 - Ni-Re-Nb-CrMo 1375 1200 ;

4.

, , - ;

5.

1200 , , .

VII « », 110 .. (, 29 ­ 2 2012 ), «2012» (, .., 9 ­ 13 2012 ), «-2013» (, .., 8 ­ 13 2013 ), X - (, . , 02 ­ 05 2013 .), XII International Conference on Cristal Chemistry of Intermetallic Compounds (Lviv, Ukraine, September 22 ­ 26, 2013), 4-th International conference HighMatTech (October 7 ­ 11, 2013, Kiev, Ukraine). 8 , 2 , , 6 . : , , ,
6


, - , , , , . , , , . , ( , , ), , , . 158 , 31 82 . 167 . . , , , , , -, - , V-VI , , , , , , . , , . - , , - . (, , 99,95 . %; , , 99,80 . %) c .
7


, , . . V-VI 1375 1200 . Ni-Re-Nb-Cr-Mo 1375 500 1200 1000 . 1375 48 1200 24 . - , [1]. () - () «LEO EVO 50 XVP» (arl Zeiss), «Inca Energy 450» (Oxford Instruments), 20 . «STOE STADI P» (Ge-, CuK1), «-4» CuK 1- (Ge-). STOE WinXPOW v.1.06 FullProf. «Jupiter STA 449 F1» (Netzsch GmbH). (p = 105 ) 20 /. 1 . «Buehler micromet 5103» 0,9807 . 10 .

8


, 1375 24 , 1200 50 . «LEO EVO 50 XVP» (arl Zeiss), «Inca Energy 450». «Adventurer Ohaus RV214» ( 0,1 , ±0,3 ) . , , , 1 . (w, %) . . , V-VI Ni-Re-Nb-Cr-Mo V-VI 1375 K [2, 3]. 5 , Ni-Re-Nb-Mo 1375 : 1. , ( 1). 2. ( ) .

9


) ) 1. ) ) 1375 : ) Ni-Re-Mo; ) Ni-Re-Nb; ) Ni-Nb-Mo; ) Re-Nb-Mo. 1 Ni-Re-Nb-Mo 1375 , ( ) 3. (Cu), (TiAl3), P (Cr9Mo21Ni20), (Cr
0,49

Fe

0,51

),

(-Mn), (W), (MoNi), Re (Mg) (W6Fe7), 2 . 2 3 , 4 ( , ). µ++ ( 2 ) , , . , , ( 2 ).
_____________________________

1

­ n- , (N-1) N- ­ N- (N2) ,

(n-1)- , n- .
2

n- N- .
3

­ N- n- , ­ , n- N-

(n+1)- (N-1)- .
4

, N- (N-1)- .

10


4. , , . Ni-Re-Nb-Mo 1375 , 1. 2. Ni-Re-Nb-Mo 1375 : ) ; ) ++; ) .

)

)

)

, , . Ni-Re-Me1-Me2 Ni-Cr-Me1-Me2 (Me1 Me2 ­ V-VI ) , , Ni-Cr-Nb-Mo [3], + +P Ni-Re-Nb-Mo. , 3. , , , , ( 3 ). . Ni-Re-Nb-Mo , + +P. , 3 .
_____________________________
1

N- ­ (n+1)- N-

, n+1 n- , (n+1) , .. N- n- , (n+1)- .

11


) ) ) 3. Ni-Re-Nb-Mo 1375 : ) + +P; ) ; ) ( ( 1), ).
5. . ( 1, 4) , Ni-Re-Nb-Mo 1375 ( 3 ).

)

)

)

)

)

)

4. Ni-ReNb-Mo: ) 1; ) 2;) 3; ) 4; ) 5; ) 6, ) 7.

)
12


1. Ni-Re-Nb-Mo 1375 , . % Ni Re Nb Mo 1 61,3 13,3 11,5 13,9 P+ + 2 48,4 4,4 8,7 38,5 ++P 3 39,8 33,1 13,6 13,5 + + 4 42,7 37,2 10,9 9,2 +P++Re 5 40,4 11,5 7,3 40,8 + + P 6 35,4 20,5 27,4 16,7 + + 7 34,1 43,1 6,1 16,7 + +P
Ni-Re-V-Nb Ni-Re-Nb-Mo









Ni-Re-V-Nb, Ni-Re-V-Ta, NiRe-Nb-Ta, Ni-Re-Nb-Cr, Ni-Re-Nb-W, Ni-Re-Ta-Cr, Ni-Re-Ta-Mo, Ni-Re-Ta-W 1375 . , 5.
Ni-Re-Nb-Cr

,

(µ++) Ni-Re-V-Ta Ni-Re-Ta-Mo Ni-Re-Ta-Cr

(NiTa2+µ+) (+Ni2Ta+ , NiTa2++ ) Ni-Re-Ta-W Ni-Re-Nb-W Ni-Re-Nb-Ta

(Re++, ++Ni2Ta, ++, ++, Re++) (µ++) (NiTa2+µ+)

5. Ni-Re-V-Nb, Ni-Re-Nb-Mo, Ni-Re-Nb-Cr, Ni-ReV-Ta, Ni-Re-Ta-Mo, Ni-Re-Ta-Cr, Ni-Re-Ta-W, Ni-Re-Nb-W, Ni-Re-Nb-Ta 1375 ( ).
13


, Ni-Re-Nb-Cr, Ni-Re-Nb-Mo, Ni-Re-Cr-Mo, Ni-Nb-Cr-Mo, Re-Nb-Cr-Mo 1200 Ni-Re-Nb-Cr-Mo 1375 1200 . Ni-Re-Nb-Cr-Mo P+ ++Re+ , ++++ 1200 ( 6 , ). 1375 ( 6 )

P+ ++Re+ , ++++ , P+ +'++, P++'++

)

)

)

6. Ni-Re-Nb-Cr-Mo: ) 1375 ; ) 1200 ; ) 1200 . (-) Ni-Re-NbCr-Mo 1200 1375 , , , , P , 1200 '. , -, , , . 1375 1200 Ni-Re-Nb-Cr-Mo , Ni - Zi = Xi / (1 ­ XNi), Xi ­ i , X
14
Ni

­

, Zi = 1.


, . , /(+Re), /(+), /(+), /(+), /(+P), /(+') Ni-Re-Nb-Cr-Mo : XNi = ZRe*ARe+ZNb*A +ZRe*ZMo*A
ReMo Nb

+ZCr*ACr +ZMo*A
NbCr

Mo

+ZRe*ZNb*A
NbMo

ReNb

+ZRe*ZCr*A
CrMo,

ReCr

+ (1)

+ZNb*ZCr*A

+ZNb*ZMo*A

+ZCr*ZMo*A

XNi ­ , ZMe ­ ( ZRe+ZNb+ZCr+ZMo=1), AMe ­ Ni Ni-Me, AMe1Me2 ­ . Ni-Nb-Cr NiNb. - , Ni3Nb. Ni-Nb-Cr , /(+), , Ni-Cr, , 1 . . , X X
Nb Nb

= B + DMe*X

Me

+F

Me

X

2

Me

,

(2) ­

­ Nb, B ­ Nb
Me

Ni-Nb, DMe, F

­ , X

Me

, Me ­ Mo, Cr, Re. Ni-Re-Nb-Cr-Mo : X
Nb

= B+ DRe*XRe + FRe*X
2 Mo

2

Re

+ DCr*XCr + FCr*X
ReMo Ni

2

Cr

+ DMo*X
CrMo

Mo

+ (3)
Nb

+ FMo*X

+F

ReCr

*XRe *XCr + F

*XRe *X

Mo

+F

*XCr *XMo. X = (100 ­ XNi) * Z

X

Zi X
Cr Mo

= (100 ­
Mo

XNi) * ZNb, XRe = (100 ­ XNi) * ZRe, XCr = (100 ­ XNi) * Z Ni-Re-Nb-Cr-Mo : (100-XNi)2 *(FRe*Z2Re+FCr*Z2Cr+FMo*Z2Mo+F

,

, ZRe+ZNb+ZCr+ZMo= 1, /(+)
ReMo*ZRe*ZMo+FReCr

*ZRe*ZCr +

15


+FMoCr*ZMo*ZCr)+(100 ­ XNi)*( ­ ZNb+DRe*ZRe+DCr*ZCr + DMo*ZMo)+B=0.

(4)

Solver Libreoffice Calc 1 4, , . 4 2. 2. 4, /(+) Ni-Re-Nb-Cr-Mo 1375 1200 . , 1375 B 11,590 FCr DRe 0,468 FMo DCr -0,277 FReCr DMo -0,622 FReMo FRe -0,080 FCrMo 1200 0,001 B 11,540 FCr 0,030 DRe -0,732 FMo -0,005 DCr -0,501 FReCr -0,023 DMo -1,006 FReMo 0,001 FRe 0,076 FCrMo 0,007 0,047 -0,006 0,014 0,053 ,

, Ni- . Ni-Re-Nb-Mo, Ni-Re-Cr-Mo, Ni-Nb-Cr-Mo, Ni-Re-Nb-Cr 1375 1200 ( 7).

)

)

)

)

7. , Ni-Re-Nb-Cr-Mo 1375 ( ) 1200 ( ) : ) Ni-Nb-Cr-Mo; ) Ni-Re-Nb-Cr; ) Ni-Re-Nb-Mo; ) Ni-Re-Cr-Mo.
16


, 1 4, Ni-Re-Nb-Cr-Mo 1375 1200 , ( 8).

)

)

)

8. Ni-Re-Nb-Cr-Mo: ) 1375 ; ) 1200 ; ) /(+) 1200 . 1375 , Zi. 1200 , . --, . , , - Ni-Nb-Mo, Ni-Cr-Mo, Ni-Cr-Re, Ni-Nb-Re, Ni-Cr-Nb Ni-Re-Mo ( 9). . ( 1375 ), , 1200 , :
17


H = A*Zi2 + B*Zi + C, .

(5)

H ­ , HV 0,1; Zi ­ i-; A, B, C ­

Ni-Nb-Mo

Ni-Cr-Mo

Ni-Cr-Re

Ni-Nb-Re

Ni-Cr-Nb

Ni-Re-Mo

9. ­ ­ Ni-Nb-Mo, Ni-Cr-Mo, Ni-Cr-Re, Ni-Nb-Re, Ni-Cr-Nb, Ni-Re-Mo 1375 1200 . ­ ­ , . , . Ni-Nb-Mo, Ni-Cr-Mo, Ni-Cr-Re, Ni-Nb-Re, Ni-Cr-Nb, Ni-Mo-Re Ni-Nb-Mo (624,1 ± 1,6 HV 0,1 Ni74,4Nb4,4Mo21,2) (614,9±2,2 HV 0,1 Ni73,6Nb8,4Mo18,0) 1200 . +. - 10.
18


)

)

)

10. - : ) 1 (Ni72,3Nb11,1Cr5,5Mo11,1); ) 8 (Ni68,3Re3,2Nb6,3Cr22,2); ) 14 (Ni72,4Re2,7Nb6,9Cr16,6Mo1,4). + Ni-Re-Nb-Cr, Ni-Re-Nb-Mo, Ni-Nb-Cr-Mo Ni-Re-NbCr-Mo (443,5 ±1,1 HV 0,1) (1200 ) 72,3 . Ni %, 11,1 . % Nb, 5,5 . % Cr, 11,1 . % Mo ( 10 ). , Ni-Nb-Mo. + Ni-Re-Nb-Cr, NiRe-Nb-Mo, Ni-Nb-Cr-Mo Ni-Re-Nb-Cr-Mo . 269,4±1,7 443,5 ±1,1 HV 0,1, a Ni-Re-Nb-Cr-Mo 286,2±1,7 320,2±1,0 HV 0,1. , , , . - . . 1200 , , Ni-Re-Nb-Cr-Mo,
19


, , 1200 . , , , 2,5 20,0 . % ( 41,5 % ) , . Ni78,3Re1,7Mo13,3Cr6,7 Ni70,0Mo10,0Cr20,0. , 2,5 . % , , 6,7 ­ 7,5 . % . , , , . Ni-Nb-Cr NiRe-Cr , , 20 .%. , Nb Mo Re, ; . Ni87,5Nb7,5Mo5,0 Ni90,0Re2,5Nb7,5 NiO Nb2O5 ( 11 , ). , , , 2,5 .%, : Ni90,0Nb10,0, Ni84,9Re1,7Nb6,7Cr6,7 Ni65,0Re1,4Nb1,3Mo2,3Cr30,0. Ni90,0Re10,0 , ( 11 ). ( 10,0 . %) Ni-Re-Nb Ni-Re-Mo, , , .
20


)

)

)

11. : ) Ni90,0Re2,5Nb7,5 (1 ­ , 2 ­ ); ) Ni90,0Re2,5Nb7,5 (1 ­ , 2 ­ ); ) Ni90,0Re10,0 (1 ­ , 2 ­ NiO, 3 ­ , ) Ni88,3Re6,7Nb1,7Mo3,3 , , Ni90,0Re10,0 : ( 1), , ( 2), . , , , . , , , - . , (+) , , , , . 1 (Ni72,3Nb11,1Cr5,5Mo11,1), 8 (Ni68,3Re3,2Nb6,3Cr22,2) 14 (Ni72,4Re2,7Nb6,9Cr16,6Mo1,4) 12. - 8 ( 12 ), (122,98 ) 0,0710 %. , 8 , 1200 .
21


)

)

)

12. : ) 1 (Ni72,3Nb11,1Cr5,5Mo11,1); ) 8 (Ni68,3Re3,2Nb6,3Cr22,2); ) 14 (Ni72,4Re2,7Nb6,9Cr16,6Mo1,4). : 1 ­ , 2 ­ . , 1200 , . , , , ± 1,5 %. 1. - , V ­ VI 1375 , -Ni3(Nb,Ta): Ni-Re-V-Nb; Ni-Re-V-Ta; Ni-Re-Nb-Ta; Ni-Re-Cr-Nb; Ni-Re-Mo-Nb; Ni-Re-W-Nb;Ni-Re-Cr-Ta; Ni-Re-Mo-Ta; Ni-Re-W-Ta. 2. Ni-Re-Nb-CrMo 1375 1200 . , 1375 ( Ni) , , , , P, Re P+ ++Re+ , 1200 3.
Ni



P+ +'++ '. Ni-Re-Mo-Nb-Cr 1375 1200 , , .
22


4.

, - , - - . - Ni-Nb-Mo, Ni-Cr-Mo, Ni-Cr-Re, Ni-Nb-Re, Ni-CrNb, Ni-Mo-Re. , + (624,1 ± 1,6 HV 0,1) + (614,9±2,2 HV 0,1) Ni-Nb-Mo.

5.







-





- Ni-Re-Nb-Cr, Ni-Re-NbMo, Ni-Nb-Cr-Mo Ni-Re-Nb-Cr-Mo. , , -, . 6. , 1200 Ni-Re-Nb-Cr-Mo 41,5 %, , . , -, . 1. Reed R.C. The Superalloys. Fundamentals and Applications. ­ Cambridge: Cambridge University Press, 2006. ­ 372 p. 2. Slyusarenko E.M., Sofin M.V., Kerimov E.Yu. Analysis of the phase equilibria in multicomponent systems using graphs. / Mendeleev Communications. ­ 1999. ­ 2. ­ P. 56 ­ 59. 3. Sofin, M.V., Kerimov, E.Yu., Chastukhin, A.E., Bazhanova, N.A., Balykova, Yu.V., Slyusarenko E.M. Determination of phase equilibria in the Ni-V-Nb-TaCr-Mo-W system at 1375 K using the graph method. // J. of Alloys and Compounds. ­ 2001. ­ 321. ­ P. 102 ­ 131. : 1. .., .., .. Ni-Nb-Mo-Re 1375 K // . ­ 2013. ­ 7. ­ . 3 ­ 10. 2. .., .., .. Ni-Re-W-V, Ni-Re-W-Nb, Ni-Re-W-Ta, Ni-ReW-Cr Ni-Re-W-Mo 1375 // . 2. . ­ 2013. ­ . 54, 4. ­ C. 234 ­ 241.
23


3.

4.

5.

6.

7.

8.

.., .., .. -- 1375 // : VII , 110- .. (29 ­ 2 2012 ). ­ , 2012. ­ . 142. .., .. Mo-Nb-Ni-Re 1375 . // «2012»: XIX , «» (, .., 9 ­ 13 2012 ). . / . . .. , .. , .. , .. . [ ]. ­ .: , 2012. ­ . 290. .. Ni-Re-V-Nb-TaCr-Mo-W 1375 // «-2013» (, .., 8 ­ 13 2013 ). . , / . . .. , .. , .. , .. , .. . [ ]. ­ .: , 2013. ­ . 32. .., .., .., .. V-VI // X - : 2 . 2. ­ : . . . -, 2013. ­ . 32 ­ 36. Nikolaev S.V., Kerimov E.Yu., Slyusarenko E.M. Polyhedration of the phase diagram of the eight-component system Ni-Re-V-Nb-Ta-Cr-Mo-W at 1375 K // Collected abstracts of the XII International Conference on Cristal Chemistry of Intermetallic Compounds (Lviv, Ukraine, September 22 ­ 26, 2013). ­ Lviv: Ivan Franko National University of Lviv, 2013. ­ . 71. Kerimov E.Yu., Nikolaev S.V., Kuznetsov V.N., Slyusarenko E.M. Multicomponent phase diagrams as basis for complex alloying nickel-based superalloys // 4-th International conference HighMatTech: Proceedings of the conference (October 7 ­ 11, 2013, Kiev, Ukraine). ­ Kiev, 2013. ­ . 84.

..., ... .. ..., .. . , ... .. , , ... .. .. , .

24