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Современные проблемы химии Курсы по выбору на английском языке
Курс по выбору
"Selected chapters of chemistry: novel promising materials"
Лекторы
Истомин С.Я. доц., к.х.н.; Чаркин Д.О. доц., к.х.н.; Уточникова В.В. н.с., к.х.н.; Елисеев А.А. с.н.с., к.х.н.; Цымбаренко Д.М. м.н.с., к.х.н.; Малахо А.П. в.н.с., к.х.н..; Кепман А.В. в.н.с., к.х.н.; Караханов Э.А. проф., д.х.н.; Зоров Н.Б., проф., д.х.н.; Столяров А.В. д.ф.-м.н., зав. каф.
Аннотация курса
Лекция
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Лектор, кафедра
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Аннотация
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1. Materials for solid oxide fuel cells. Презентация лекции
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Истомин С.Я. доц.,
к.х.н., каф. неорганической химии
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Nowadays solid
oxide fuel cell (SOFC) is considered as one of the most prospective
alternative energy source. Recent advances in the field of research and
development of materials for SOFC are discussed in the lecture. Special
attention is payed to cathode materials for intermediate temperature SOFC.
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2. Crystal chemical design and tailored
synthesis of layer-type inorganic materials.
Презентация лекции
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Чаркин Д.О., доц., к.х.н., каф.
неорганической химии
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The lecture is dedicated to application
of modular approach, a modern powerful tool of structural design, to tailored
synthesis of several promising families of inorganic materials. Its
application to inorganics with complex layered structures will be addressed
in detail. Examples include layered perovskites based on multinary bismuth
oxides, and layered anti-fluorites based on transition-metal chalcogenides
and pnictides
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3. Luminescent properties of coordination
compound. Презентация лекции
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Уточникова В.В.
н.с., к.х.н.
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Luminescence still finds new applications
in the modern world, and a special place among the luminescent materials
belongs to the coordination compounds. Purposeful synthesis of brightly
luminescent compounds requires an understanding of the fundamental features
of their luminescent properties. During the lecture the processes affecting
the luminescence will be analyzed, and the approaches to the design of
coordination compounds will be presented based on this analysis.
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4. Self-assembly
for functional nanomaterials.
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Елисеев А.А., с.н.с., к.х.н.
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The lecture concerns the development of
self-assembly, conservative and dissipative self-organization processing at
nanolevel for design of spatially ordered and correlated nanomaterials.
The pathways for externally and internally
controlled self-assembly are given in examples of synthesis of photonic
crystals and self-ordered nanostructure arrays. Replication processes
for the formation of functional nanomaterials in nanoreactors including
single-walled carbon nanotubes, zeolites, mesoporous molecular sieves, anodic
alumina templates are discussed. Conservative and dissipative
self-organization examples in the synthesis of ordered nanostructures are
reviewed and the possibilities of structural control at the bifurcation point
are given. The benefits of structural ordering for functional properties of
nanomaterials are discussed
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5. Coordination chemistry
approaches for synthesis of inorganic materials.
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Цымбаренко Д.М., м.н.с., к.х.н.
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The prospects material sciences are
closely connected with possibilities of coordination chemistry. Coordination
compounds are widely used as precursors for soft chemical synthesis of
powders, nanoparticles, thin films and heterostructures from vapor phase and
solutions. The present lecture deals with modern techniques for production
electronic, optical, magnetic and superconducting materials. The base
principles of CVD, ALD and CSD, the vigorously developed techniques of thin
film deposition, and approaches to design of metal-organic precursors will be
discussed
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6. Сhemical technology and chemical
equipment.
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Малахо А.П. в.н.с., к.х.н.
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The lecture is devoted to the general aspects of chemical
production. Equipment for main technological operations will be briefly
presented including: transfer of solids, fluids and gases, heat transfer,
drying and cooling, mixing and agitation, solid-liquid separation,
disintegration, agglomeration, size separation of particulate solids, the
processes of distillation, rectification and extraction.
Part of the discourse will involve analysis of design for
chemical reactors, process vessels and material transfer systems. Then,
examples of typical chemical production and applied equipment will be analyzed.
The lecture will be finalized by description main technical
documents required for chemical production, order for development and approval
of them. Some aspects of technical regulation policy in Russia are presented.
Перевод
Лекция
посвящена общим аспектам химического производства. В ходе лекции будут
рассмотрены основные химико-технологические операции, включая транспортировку
твердых, жидких и газообразных продуктов, теплообмен, сушка и охлаждение,
смешение, фазовое разделение, измельчение, агломерация и рассев, дистилляция,
экстракция и ректификация.
Отдельный
раздел лекции посвящен анализу конструкции химических реакторов,
технологических аппаратов и систем транспорта продуктов. Также будет рассмотрен
ряд типовых технологических процессов.
В
завершении, рассматривается основная техническая документация, требуемая для
химического производства, порядок ее создания и согласования. Кратко приводятся
связанные с технологией требования органов технического регулирования
Российской Федерации.
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7. Carbon
materials
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Малахо А.П.
в.н.с., к.х.н.
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Carbon has several material forms which are known
aspolymorphs (or allotropes). They are composed entirely of carbon but have different
physical structures and, uniquely to carbon, have different names: graphite,
diamond, lonsdalite, fullerene, amorphous carbon and others.To describe a
'carbon' material, the termis used in the lecture is also with a qualifier of
material such as carbon fiber, pyrolytic carbon, vitreous carbon, carbon black
and others.However the focus of this lecture is the carbon and not its
compounds.
The course of lecture will pass through the technological
cycles of carbon materials production: starting from raw products (coal,
natural graphite, oil, polymers etc.) via intermediate materials (carbon
fibers, tar pitches, coke) to complicated or special materials (artificial
graphite, nanotubes, carbon composites, carbon films).
Survey of industrial application of carbon materials will
cover general technological processes, like metallurgy and chemical industry,
energy sector with power generation, atomic industry, oil and gas sector. High
tech application of carbon in aerospace and electronic industries will be also
discussed.
Перевод
Углерод
имеет различные полиморфные и аллотропные состояния. Эти формы состоят из углерода,
но имеют различные физико-химические свойства и носят различные названия:
графит, алмаз, лонсдейлит, фуллерен, аморфный углерод и другие. В рамках данной
лекции также рассмотрены такие виды углеродных материалов как углеродные
волокна, пиролитический углерод, стеклоуглерод, углеродная сажа и другие. В то
же время в рамках лекции не будут затрагиваться многочисленные вещества и
соединения, содержащие углерод наряду с другими элементами.
В
ходе лекции будут рассмотрены наиболее распространенные технологические
маршруты производства углеродных материалов, начиная с природных источников
углерода, таких как уголь, нефть, полимеры, природный графит и т.д., с
рассмотрением образующихся промежуточных продуктов, таких как пеки, углеродные
волокна, коксы и др. до сложных и высокотехнологичных материалов -
искусственных графитов, углеродных композитов, нанотрубок и тонких пленок.
Обзор
промышленных применений углеродных материалов будет включать наиболее крупные
технологические направления, такие как металлургия и химическая промышленность,
добыча нефти и газа, тепловая и атомная энергетика. Также будут рассмотрены
высокотехнологические материалы для авиакосмического применения и электроники.
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8. Polymer Composite materials
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Кепман А.В., с.н.с., к.х.н.
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9. Molecular recognition Catalysis.
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Караханов Э.А., проф., д.х.н.
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Over the past few decades significant
research has been directed toward the development of new methods for design of
new selective catalysts. Among them, the potential of homogeneous catalysis
with molecular recognition abilities has been steadily demonstrated, as they
provide a direct and selective way toward the selective transformation of
different organic substrates.
Molecular recognition of a substrate results
from the read out of specific information concerning the substrate or
transition state to be bound, which is stored at the molecular level within the structure
of the receptor molecule or material. The catalysis involves a binding
step for which molecular recognition is a prerequisite, followed by
the chemical transformation of the substrate
bound within supramolecular complex. The present lecture deals with a
strategy of design of catalyst with molecular recognition abilities based on
receptor molecules (cyclodextrines, calizarenes etc.) and molecular imprinting
polymers use.
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10. Design of hybrid mesoporous materials for
catalytic applications.
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Караханов Э.А., проф., д.х.н.
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The integration of unique functionality
into mesoporous organic-inorganic hybrid materials is an important issue in
solving the challenges of development of new selective heterogeneous metal
complex and nanoparticle catalysts. Traditional heterogeneous catalysts are rather
limited in the
nature of their active sites and thus the scope of reactions that they can
accomplish. Soluble metal complex or nanoparticle based catalysts can
catalyze a much larger variety of reaction types than traditional solid
catalysts but suffer from high degree of difficulty to be recycled. The
immobilization of metal complexes and nanoparticles onto solids to create
organic- inorganic hybrid catalysts can be accomplished with some aspects
of design that
will be discussed in the lecture by the example of the organic-inorganic mesoporous hybrids
with regular structure.
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11. Laser-Induced Breakdown Spectrometry
for analysis of solid samples.
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Зоров Н.Б. проф., д.х.н.
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The lecture is devoted to one of the most
widely used modern laser analytical methods - Laser-Induced Breakdown
Spectrometry (LIBS). Fundamentals and the instrumentation are presented. The
key advantages of providing its high efficiency are shown. Unique
capabilities of this technique make it suitable for rapid analysis of solid
samples like metals and alloys, glasses, polymers, objects of cultural
heritage and various environmental samples. A striking example of this is the
analysis of samples on the Martian surface by the LIBS instrument installed
on the Curiosity rover
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12. Ultracold
molecules - laser synthesis and manipulation.
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Столяров А.В., зав.каф., д.ф.-м.н.
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We discuss high-precision methods of laser spectroscopy and state
of the art electronic structure calculations used to optimize multistep laser
synthesis and to stabilize ultracold molecular ensembles in their absolute
ground state.
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Сервер
создается при поддержке Российского
фонда фундаментальных исследований
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Вебдизайн: Copyright (C) И. Миняйлова и В. Миняйлов
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