Лекция

Лектор, кафедра

Аннотация

1. Materials for solid oxide fuel cells. Презентация лекции

Истомин С.Я. доц., к.х.н., каф. неорганической химии

Nowadays solid oxide fuel cell (SOFC) is considered as one of the most prospective alternative energy source. Recent advances in the field of research and development of materials for SOFC are discussed in the lecture. Special attention is payed to cathode materials for intermediate temperature SOFC.

2. Crystal chemical design and tailored synthesis of layer-type inorganic materials. Презентация лекции

Чаркин Д.О., доц., к.х.н., каф. неорганической химии

The lecture is dedicated to application of modular approach, a modern powerful tool of structural design, to tailored synthesis of several promising families of inorganic materials. Its application to inorganics with complex layered structures will be addressed in detail. Examples include layered perovskites based on multinary bismuth oxides, and layered anti-fluorites based on transition-metal chalcogenides and pnictides

3. Luminescent properties of coordination compound. Презентация лекции

Уточникова В.В. н.с., к.х.н.

Luminescence still finds new applications in the modern world, and a special place among the luminescent materials belongs to the coordination compounds. Purposeful synthesis of brightly luminescent compounds requires an understanding of the fundamental features of their luminescent properties. During the lecture the processes affecting the luminescence will be analyzed, and the approaches to the design of coordination compounds will be presented based on this analysis.

4. Self-assembly for functional nanomaterials.

Елисеев А.А., с.н.с., к.х.н.

The lecture concerns the development of self-assembly, conservative and dissipative self-organization processing at nanolevel for design of spatially ordered and correlated nanomaterials.

The pathways for externally and internally controlled self-assembly are given in examples of synthesis of photonic crystals and self-ordered  nanostructure arrays. Replication processes for the formation of functional nanomaterials in nanoreactors including single-walled carbon nanotubes, zeolites, mesoporous molecular sieves, anodic alumina templates are discussed. Conservative and dissipative self-organization examples in the synthesis of ordered nanostructures are reviewed and the possibilities of structural control at the bifurcation point are given. The benefits of structural ordering for functional properties of nanomaterials are discussed

5. Coordination chemistry approaches for synthesis of inorganic materials.

Цымбаренко Д.М., м.н.с., к.х.н.

The prospects material sciences are closely connected with possibilities of coordination chemistry. Coordination compounds are widely used as precursors for soft chemical synthesis of powders, nanoparticles, thin films and heterostructures from vapor phase and solutions. The present lecture deals with modern techniques for production electronic, optical, magnetic and superconducting materials. The base principles of CVD, ALD and CSD, the vigorously developed techniques of thin film deposition, and approaches to design of metal-organic precursors will be discussed

6. Сhemical technology and chemical equipment.

Малахо А.П. в.н.с., к.х.н.

The lecture is devoted to the general aspects of chemical production. Equipment for main technological operations will be briefly presented including: transfer of solids, fluids and gases, heat transfer, drying and cooling, mixing and agitation, solid-liquid separation, disintegration, agglomeration, size separation of particulate solids, the processes of distillation, rectification and extraction.

Part of the discourse will involve analysis of design for chemical reactors, process vessels and material transfer systems. Then, examples of typical chemical production and applied equipment will be analyzed.

The lecture will be finalized by description main technical documents required for chemical production, order for development and approval of them. Some aspects of technical regulation policy in Russia are presented.

Перевод

Лекция посвящена общим аспектам химического производства. В ходе лекции будут рассмотрены основные химико-технологические операции, включая транспортировку твердых, жидких и газообразных продуктов, теплообмен, сушка и охлаждение, смешение, фазовое разделение, измельчение, агломерация и рассев, дистилляция, экстракция и ректификация.

Отдельный раздел лекции посвящен анализу конструкции химических реакторов, технологических аппаратов и систем транспорта продуктов. Также будет рассмотрен ряд типовых технологических процессов.

В завершении, рассматривается основная техническая документация, требуемая для химического производства, порядок ее создания и согласования. Кратко приводятся связанные с технологией требования органов технического регулирования Российской Федерации.

7. Carbon materials

Малахо А.П. в.н.с., к.х.н.

Carbon has several material forms which are known aspolymorphs (or allotropes). They are composed entirely of carbon but have different physical structures and, uniquely to carbon, have different names: graphite, diamond, lonsdalite, fullerene, amorphous carbon and others.To describe a 'carbon' material, the termis used in the lecture is also with a qualifier of material such as carbon fiber, pyrolytic carbon, vitreous carbon, carbon black and others.However the focus of this lecture is the carbon and not its compounds.

The course of lecture will pass through the technological cycles of carbon materials production: starting from raw products (coal, natural graphite, oil, polymers etc.) via intermediate materials (carbon fibers, tar pitches, coke) to complicated or special materials (artificial graphite, nanotubes, carbon composites, carbon films).

Survey of industrial application of carbon materials will cover general technological processes, like metallurgy and chemical industry, energy sector with power generation, atomic industry, oil and gas sector. High tech application of carbon in aerospace and electronic industries will be also discussed.

Перевод

Углерод имеет различные полиморфные и аллотропные состояния. Эти формы состоят из углерода, но имеют различные физико-химические свойства и носят различные названия: графит, алмаз, лонсдейлит, фуллерен, аморфный углерод и другие. В рамках данной лекции также рассмотрены такие виды углеродных материалов как углеродные волокна, пиролитический углерод, стеклоуглерод, углеродная сажа и другие. В то же время в рамках лекции не будут затрагиваться многочисленные вещества и соединения, содержащие углерод наряду с другими элементами.

В ходе лекции будут рассмотрены наиболее распространенные технологические маршруты производства углеродных материалов, начиная с природных источников углерода, таких как уголь, нефть, полимеры, природный графит и т.д., с рассмотрением образующихся промежуточных продуктов, таких как пеки, углеродные волокна, коксы и др. до сложных и высокотехнологичных материалов - искусственных графитов, углеродных композитов, нанотрубок и тонких пленок.

Обзор промышленных применений углеродных материалов будет включать наиболее крупные технологические направления, такие как металлургия и химическая промышленность, добыча нефти и газа, тепловая и атомная энергетика. Также будут рассмотрены высокотехнологические материалы для авиакосмического применения и электроники.

8. Polymer Composite materials

Кепман А.В., с.н.с., к.х.н.

9. Molecular recognition Catalysis.

Караханов Э.А., проф., д.х.н.

Over the past few decades significant research has been directed toward the development of new methods for design of new selective catalysts. Among them, the potential of homogeneous catalysis with molecular recognition abilities has been steadily demonstrated, as they provide a direct and selective way toward the selective transformation of different organic substrates.

Molecular recognition of a substrate results from the read out of specific information concerning the substrate or transition state to be bound, which is stored at the molecular level within the structure of the receptor molecule or material. The catalysis involves a binding step for which molecular recognition is a prerequisite, followed by the chemical transformation of the substrate bound within supramolecular complex. The present lecture deals with a strategy of design of catalyst with molecular recognition abilities based on receptor molecules (cyclodextrines, calizarenes etc.) and molecular imprinting polymers use.

10. Design of hybrid mesoporous materials for catalytic applications.

Караханов Э.А., проф., д.х.н.

The integration of unique functionality into mesoporous organic-inorganic hybrid materials is an important issue in solving the challenges of development of new selective heterogeneous metal complex and nanoparticle catalysts. Traditional heterogeneous catalysts are rather limited in the nature of their active sites and thus the scope of reactions that they can accomplish. Soluble metal complex or nanoparticle based catalysts can catalyze a much larger variety of reaction types than traditional solid catalysts but suffer from high degree of difficulty to be recycled. The immobilization of metal complexes and nanoparticles onto solids to create organic- inorganic hybrid catalysts can be accomplished with some aspects of design that will be discussed in the lecture by the example of the organic-inorganic mesoporous hybrids with regular structure.

11. Laser-Induced Breakdown Spectrometry for analysis of solid samples.

Зоров Н.Б. проф., д.х.н.

The lecture is devoted to one of the most widely used modern laser analytical methods - Laser-Induced Breakdown Spectrometry (LIBS). Fundamentals and the instrumentation are presented. The key advantages of providing its high efficiency are shown. Unique capabilities of this technique make it suitable for rapid analysis of solid samples like metals and alloys, glasses, polymers, objects of cultural heritage and various environmental samples. A striking example of this is the analysis of samples on the Martian surface by the LIBS instrument installed on the Curiosity rover

12. Ultracold molecules - laser synthesis and manipulation.

Столяров А.В., зав.каф., д.ф.-м.н.

We discuss high-precision methods of laser spectroscopy and state of the art electronic structure calculations used to optimize multistep laser synthesis and to stabilize ultracold molecular ensembles in their absolute ground state.