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- , , .. . : , , , , . The synthesis and application of the new generation functional copolymers of alternating copolymers of carbon monoxide with vinyl and diene monomers by catalytic copolymerization are discussed. Key words: alternating copolymers, carbon monoxide, olefins, dienes, catalytic copolymerization.

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2004 : 1 - ; 2 - , ( ) ; 3 - , ( , ) ; 4 - , ; 5 - , Pd, , . 6 - . ( 1987 1990 1991 ).

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1. 2. 3. 4. Sen A., Adv. Polym. Sci., 1986, v.73/74, 125. Sen A., Acc. Chem. Res., 1993, v.26, 303. Drent E., Budzelaar P.H.M., Chem. Rev., 1996, 96, 663. Belov G.P., in book "Polymeric Materials Encyclopedia", CRC Press, Inc. USA, 1996, 4714.

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57



5. Drent E., van Broekhoven J.A.M., Budzelaar P.H.M., in book "Applied Homogeneous Catalysis with Organometallic Compounds", VCH, Weinheim, 1996, v.1, 333. Sommazzi A., Garbassi G., Progr. Plym. Sci., 1997, v.22, 1547. Belov G.P., Polymer Sci., 1998, v.40-B, 89. Nozaki A., Hijama T., J. Organomet. Chem., 1999, v.576, 248. Belov G.P., Polymer Sci., 2001, v.43, 46. Belov G.P., Kinetic and Catalysis, 2001, v.42, 301. Drent E., Mul W.P., Smardijk A.A., in book "Encyclopedia of Polymer Sci. and Technol." Wiley & Son. Inc. 2001. Bianchini C., Meli A., Coord. Chem. Rev., 2002, v.225, 67. Belov G.P., Rus. Chem. Bull. Int. Ed., 2002, v.51, 1605. Sen A., in book "Catalysis by Metal Complexes", Kluwer Acad. Publ., Dordrecht, 2003. 15. Belov G.P., Novikova E.V., Russian Chemical Reviews, 2004. v.73, 267 16. Bianchini C., Meli A., in book " Mechanisms in homogeneous catalysis: a spectroscopic approach". Ed. by Brian Heaton, Wiley Publ., 2005 17. . 1997, 1, 80 18. Belov G. P., Golodkov O. N., Gumargalieva K. Z., Kalinina I. G., Semenov A. S. , 1997, 9, 40; Int. Polym. Sci. and Technol., 1998, 25, No 5, T/72. 19. Eur.Pat. 0306115.1988. 20. .. 144412. 2005 21. . 6133410. 2000 22. . 5077385.1991 23. . WO 9905201.1999 24. 4895689. 1990 25. . 4892697.1990 26. 5077385.1991

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