Документ взят из кэша поисковой машины. Адрес оригинального документа : http://mgumus.chem.msu.ru/ru/publication/02-content.pdf Дата изменения: Fri Dec 27 20:22:44 2002 Дата индексирования: Mon Oct 1 20:15:02 2012 Кодировка:

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1.1 We_f_glguckhklZ\]mfmkh\uodbkehl ...............................................15
1.1.1 We_f_glguckhklZ\]mfmkh\uodbkehljZaebqgh]h ijhbkoh`^_gby ............................................................................................ 15 1.1.2 F_lh^bq_kdb_Zki_dluwe_f_glgh]hZgZebaZ]mfmkh\uo dbkehl ......................................................................................................... 17 1.2.1 NmgdpbhgZevguckhklZ\]mfmkh\uodbkehl ...................................... 1.2.2 F_lh^bq_kdb_Zki_dlulbljbf_ljbq_kdh]hZgZebaZ ]mfmkh\uodbkehl ...................................................................................... 1.2.3 Bkke_^h\Zgb_kljmdlmjgh-]jmiih\h]hkhklZ\Zm]e_jh^gh]h kd_e_lZ^_kljmdlb\gufbf_lh^ZfbZgZebaZ ...................................... 1.2.4 Bkke_^h\Zgb_kljmdlmjgh-]jmiih\h]hkhklZ\Z]mfmkh\uo dbkehlf_lh^Zfbki_dljhkdhibbYFJ .................................................. 21 25 29 31

1.2 Kljmdlmjgh-]jmiih\hckhklZ\]mfmkh\uodbkehl ...............................21

1.3 Kljmdlmjgh-]jmiih\hckhklZ\]mfmkh\uodbkehljZaebqgh]h ijhbkoh`^_gbyih^Zgguf13KYFJ .................................................... 1.4 Ijh[e_fudhebq_kl\_gghc13&YFJ-ki_dljhkdhibb ]mfmkh\uo dbkehl ...................................................................................................... 1.5 Ki_dljhkdhibyIFJ]mfmkh\uodbkehl .............................................. 1.6 Fhe_dmeyjgh-fZkkh\uckhklZ\]mfmkh\uodbkehl ............................

35 37 45 50

1.7 HibkZgb_kljh_gby]mfmkh\uodbkehl bijh[e_fu deZkkbnbdZpbb .......................................................................................56
1.7.1 Bkihevah\Zgb_[ehd-ko_fbkljmdlmjguonhjfme^ey hibkZgbykljh_gby]mfmkh\uodbkehl .................................................... 56 1.7.2 Qbke_ggh_hibkZgb_kljh_gby]mfmkh\uodbkehl ............................ 61

1.6.1 Bkke_^h\Zgb_fhe_dmeyjgh-fZkkh\h]hjZkij_^_e_gby ]mfmkh\uodbkehlf_lh^hfwdkdexabhgghcojhfZlh]jZnbb .............. 52 1.6.2 F_lh^bq_kdb_Zki_dluhij_^_e_gbyfhe_dmeyjguofZkk ]mfmkh\uodbkehlf_lh^hfwdkdexabhgghcojhfZlh]jZnbb .............. 54

1.8 Dhfie_dkhh[jZamxsb_b^_lhdkbpbjmxsb_k\hckl\Z ]mfmkh\uodbkehlihhlghr_gbxdly`_euff_lZeeZf .....................64
1.8.1 Ih^oh^udhibkZgbxkl_obhf_ljbb\aZbfh^_ckl\by ]mfmkh\uodbkehlkly`_eufbf_lZeeZfb ........................................... 1.8.2 MklZgh\e_gb_dhgp_gljZpbbf_lZeek\yau\Zxsbop_gljh\\ jZkl\hjZo]mfmkh\uodbkehl................................................................... 1.8.3
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1.9 K\yau\Zxsb_b^_lhdkbpbjmxsb_k\hckl\Z]mfmkh\uodbkehl ihhlghr_gbxdhj]Zgbq_kdbfwdhlhdkbdZglZf ...................................77
1.9.1 K\yau\Zgb_hj]Zgbq_kdbowdhlhdkbdZglh\ ]mfmkh\ufb dbkehlZfb................................................................................................... 77 1.9.2 F_lh^bq_kdb_Zki_dluhij_^_e_gbydhgklZglk\yau\Zgby hj]Zgbq_kdbowdhlhdkbdZglh\]mfmkh\ufbdbkehlZfb ....................... 81 1.9.3 Bkke_^h\Zgb_^_lhdkbpbjmxsbok\hckl\]mfmkh\uodbkehl ihhlghr_gbxdhj]Zgbq_kdbfwdhlhdkbdZglZf................................... 82

2. =E:<:NHJFBJH<:GB? 2.1
3. =E:<:HIJ?>?E?GB?WE?F?GLGH=HKHKL:<: =MFMKH 3.1 Hij_^_e_gb_we_f_glgh]hkhklZ\Zij_iZjZlh\]mfmkh\uo dbkehl\jZkq_l_gZ[_aahevgmx[_a\h^gmxijh[m ............................97
3.1.1 Hij_^_e_gb_KGN, SbH ...................................................................... 98 3.1.2 Hij_^_e_gb_\eZ`ghklb .................................................................... 100 3.1.3 Hij_^_e_gb_h[s_cahevghklbbkhklZ\Zahevguowe_f_glh\ .. 101 3.1.4 Ko_fZh[jZ[hldb^Zgguowe_f_glgh]hZgZebaZ^eyjZkq_lZ we_f_glgh]hkhklZ\Z]mfmkh\uodbkehl............................................. 107

3.2 We_f_glguckhklZ\ij_iZjZlh\]mfmkh\uodbkehl bkihevah\Zgguo\jZ[hl_ ...................................................................110

4. =E:<:HIJ?>?E?GB?KLJMDLMJGH-=JMIIH 4.1 H^ghf_jgZyki_dljhkdhibyYFJ13KbIFJ ...................................115
4.1.1 DZq_kl\_ggZyoZjZdl_jbklbdZ13KYFJ-bIFJ-ki_dljh\ ]mfmkh\uodbkehl .................................................................................... 4.1.2
4.2 >\mf_jgZydhjj_eypbhggZyki_dljhkdhibyYFJ gZy^jZo1Gb13K ..................................................................................148
4.2.1 H[sZyoZjZdl_jbklbdZbkihevah\Zgguo\jZ[hl_^\mf_jguo ]hfh-b]_l_jhy^_jguoYFJ-wdki_jbf_glh\ ...................................... 149 4.2.2 1G1G&26<-ki_dlju ........................................................................... 151 4.2.3 1G1G72&6

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4.2.4 G K+64&ki_dlju .......................................................................... 156 4.2.5 KjZ\gbl_evgucZgZebaj_amevlZlh\^\mf_jguoYFJwdki_jbf_glh\ ......................................................................................... 160
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4.3 Hij_^_e_gb_kljmdlmjgh-]jmiih\h]hkhklZ\Zg_]b^jhebam_fhc b]b^jhebam_fhcqZklb]mfmkh\uodbkehl .........................................162

4.3.1 H^ghf_jgZyki_dljhkdhibyYFJ13K ................................................ 163 4.3.2 >\mf_jgZyki_dljhkdhibyYFJgZy^jZo1Gb13K ........................... 166 4.3.3 Hij_^_e_gb_m]e_\h^gh]hkhklZ\Z]b^jhebam_fhcqZklb ]mfmkh\uodbkehlf_lh^hf
5. =E:<:HIJ?>?E?GB?FHE?DMEYJGH-F:KKH 5.1
6. =E:<:DE:KKBNBD:PBY=MFMKH?GBXBNJ:DPBHGGHFMKHKL: 6.1 OZjZdl_jbklbdZihemq_ggh]hfZkkb\Z^Zgguo................................195 6.2 DeZkkbnbdZpbykbkihevah\Zgb_fbgl_]jZevguo^_kdjbilhjh\ khklZ\Z ..................................................................................................201 6.3 DeZkkbnbdZpbykbkihevah\Zgb_fjZkrbj_ggh]hgZ[hjZ ^_kdjbilhjh\fhe_dmeyjgh-fZkkh\h]hkhklZ\Z ................................206
6.3.1 DeZkkbnbdZpbyihf_lh^mD-[eb`Zcrbokhk_^_c ........................... 207 6.3.2 DeZkkbnbdZpbykbkihevah\Zgb_fg_cjhk_l_c ............................... 212

7. =E:<:BKKE?>H<:GB?K?LHDKBPBJMXSBOK 7.1 Bkke_^h\Zgb_dhfie_dkhh[jZamxsbok\hckl\]mfmkh\uo dbkehlihhlghr_gbxdHg(II) ..............................................................218
7.1.1 Hij_^_e_gb_kh^_j`Zgbyjlmlv-k\yau\Zxsbop_gljh\\ ]mfmkh\uodbkehlZo ................................................................................ 222 7.1.2 Hij_^_e_gb_dZ`msbokydhgklZglmklhcqb\hklbdhfie_dkh\ ]mfmkh\uodbkehlkHg(II) ....................................................................... 226

7.2 Bkke_^h\Zgb_k\yau\Zxsbok\hckl\]mfmkh\uodbkehlih hlghr_gbxI:MbZljZabgm ................................................................235
7.2.1 Hij_^_e_gb_dhgklZglk\yau\Zgby]mfmkh\uodbkehlkI:M ..... 7.2.2 Hij_^_e_gb_dhgklZglk\yau\Zgbyibj_gZ]b^jhebah\Zggufb ij_iZjZlZfb]mfmkh\uodbkehl ............................................................ 7.2.3 AZ\bkbfhklvdhgklZglk\yau\ZgbyI:M]mfmkh\ufb dbkehlZfbhljGbbhgghckbeukj_^u ................................................ 7.2.4 Hij_^_e_gb_dhgklZglk\yau\Zgby]mfmkh\uodbkehlk ZljZabghf ................................................................................................ 236 240 241 247

7.3 Dhgp_ipbydhgklZglu^_lhdkbdZpbb dZddhebq_kl\_gghc oZjZdl_jbklbdb^_lhdkbpbjmxsbok\hckl\]mfmkh\uodbkehl ........250 7.4 Bkke_^h\Zgb_^_lhdkbpbjmxsbok\hckl\]mfmkh\uodbkehlih hlghr_gbxdHg(II) ...............................................................................253
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7.4.2 Hij_^_e_gb_dhgklZgl^_lhdkbdZpbb+JII) ]mfmkh\ufb dbkehlZfb................................................................................................. 258

7.5 Bkke_^h\Zgb_^_lhdkbpbjmxsbok\hckl\]mfmkh\uodbkehlih hlghr_gbxdI:M .................................................................................262
7.5.1
7.6 Bkke_^h\Zgb_^_lhdkbpbjmxsbok\hckl\ ]mfmkh\uodbkehlih hlghr_gbxdZljZabgm .........................................................................268

7.6.1
8. =E:<:8IJH=GHAK?KDJBILHJH 8.1 Dhjj_eypbhggZy\aZbfhk\yav^_kdjbilhjh\khklZ\Zb ijh]ghabjm_fuok\hckl\ .....................................................................277 8.2 Ijh]ghklbq_kdb_fh^_ebihemq_ggu_f_lh^hf fgh`_kl\_gghcj_]j_kkbb...................................................................281 8.3 Ijh]ghklbq_kdb_fh^_ebihemq_ggu_f_lh^Zfb fgh]hdhfihg_glgh]hZgZebaZ .............................................................284

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