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Enthalpy of Formation of Y2Ba4Cu7O14.916

Enthalpy of Formation of Y2Ba4Cu7O14.916

A.S. Monayenkova, A.A. Popova, V.V. Kuzmenko, J. Karpinski, K. Conder

J.Chem.Thermod. (in print)

The molar enthalpy of reaction of the Y2Ba4Cu7O14.916 high-temperature superconductor with 1.07 N HCl has been determined by the solution calorimetry. From that value the standard molar enthalpy of formation of the Y2Ba4Cu7O14.916 at 298.15 K has been found: DfH0m (Y2Ba4Cu7O14.916, cr, 298.15 K) = ( -5446.0 +6) kJ—mol-1

Laboratory of Chemical Thermodynamics