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- . , . : , , , - . It is suggested to classify the ultra- and microfiltration processes on the base of the surface phenomena and forces to be arisen during separation. Using the Derjaguin method new quantitative theory of electrostatic and molecular interaction between colloidal particle and curved membrane surface has been developed taking into account hydrodynamic force acting at the pore entrance. Key words: Derjaguin method, electrostatic and molecular interaction, Stoke's hydrodynamic force, ultra- and microfiltration.

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1. Israelachvili J.N., Adams G.J. // J. Chem. Soc. Faraday Trans. I. 1978. V. 74, p. 975. 2. Parker J.L., Christenson H.K., Ninham B.W. // Rev. Sci. Instrum. 1989. V. 60, p. 3135. 3. Derjaguin B.V., Rabinovich Y.I., Churaev N.V. // Nature. 1978. V. 272, p. 313318.

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4. LeNeveu D.M., Rand R.P., Parsegan V.A. // Nature. 1976. V. 259, p. 101. 5. Binnig G., Rohrer H. // Helv. phys. acta. 1982. V. 55, p. 726735. 6. Binnig G., Quate C., Gerber G. Atomic force microscope // Phys. Rev. Lett. 1986. V. 56, p. 930983. 7. Wickramasinghe H.K. // Sci. Amer. 1989. Oct., p. 74 81. 8. Durig U, Gimsewski J.K., Pohl D.W. // Phys. Rev. Lett. 1986. V. 57, p. 403. 9. Martin Y., Williams C., Wickramasinghe H. // J. Appl. Phys. 1987, p. 47234729. 10. Burnham N.N., Dominguez D.D., Momery R.L., Colten R.J. // Phys. Rev. Lett. 1990. V. 64, p. 1931. 11. Weisenhorn A.L., Hansma P.K., Albrecht T.R., Quate C.F. // Appl. Phys. Lett. 1989. V. 54, p. 26512653. 12. Ducker W.A., Cook R.F. // Appl. Phys. Lett. 1990. V. 56, p. 2408. 13. Erlandsson R., Hadziiannou G., Mate C.M., McClelland G.M., Chiange S. // J. Phys. Chem. 1988. V. 89, p. 51905193. 14. Ducker W.A., Senden T.J., Pashley R.M. // Nature. 1991. V. 353, p. 239241. 15. Ducker W.A., Senden T.J. Measurement of forces in liquids using a force microscope // Langmuir. 1992. V. 8, p. 18311836. 16. Zhenge X., Yoon R. // J. Colloid and Interface Sci. 1990. V. 134, p. 427434. 17. Ottewill R.H. // In Concentrated Dispersions. Goodwin J.W.: Royal Society of Chemistry. London. 1982. 18. Hansma P.K., Elings V.B., Marti O., Bracker C.E. Scanning tunnelling microscopy and atomic force microscopy: Applications to Biology and Technology // Science. 1988. V. 242, p. 209216. 19. Albrecht T.R., Quate C.F. Atomic resolution with the atomic force microscope on conductors and nonconductors // J. Vac. Sci. and Technol. A. 1988. V. 6, p. 271275. 20. Morris V.J. Biological applications of scanning probe microscopies // Prog. Biophys. Mol. Biol. 1994. V. 61, p. 131185. 21. Fritzsche A.K., Arevalo A.R., Moore M.D., O'Hara C. The surface structure and morphology of polyacrylonitrile membranes by atomic force microscopy // J. Membr. Sci. 1993. V. 81, p. 109120. 22. Chahboun A., Coratger R., Ajustron F., Beauvillian J. Comparative study of micro- and ultrafiltration membranes using STM, AFM and SEM techniques // Ultramicroscopy. 1992. V. 41, p. 235244. 23. Bessieres A., Meireles M., Airnar P., Sanchez V., Coratger R., Beauvillain J. Surface analysis of ultrafiltration membranes by atomic force microscopy, in P. Aimar and P. Aptel (Eds.), Recent Progres en Genie des Precedes // Membrane preparation Fouling - Emerging processes. CPIC, Nancy. 1992. V. 6, p. 111116. 24. Miwa ., Yamaki M., Yoshimusa H., Ebina S., Nagayama K. Fibrous textured surface of an ultrafiltration membrane delineated by atomic force microscope // Jap. J. Appl. Phys. 1992. V. 31, p. L1495L1497. 25. Dietz P., Hansma P.K., Inacker ., Lehmann H.D., Herrmann K.H. Surface and pore structures of microand ultrafiitration membranes imaged with the atomic force microscope // J. Membr. Sci. 1992. V. 65, p. 101 111. 26. Fritzsche A.K., Arevalo A.R., Connolly A.F., Moore M.D., Elings V.B., Kjoller K., Wu C.M. The structure and morphology of the skin of polyethersulfone ultrafiltration membranes. A comparative atomic force microscope and a scanning electron microscope study // J. Appl. Polym. Sci. 1992. V. 45, p. 19451956. 27. Fritzsche A.K., Arevalo A.R., Moore M.D., Weber C.J., Elings V.B., Kjoller K., Wu C.M. Image enhancement of polyethersulfone ultrafiltration membranes surface structure for atomic force microscopy // J. Appl. Polym. Sci. 1992. V. 46, p. 167178. 28. Fritzsche A.K., Arevalo A.R., Moore M.D. Examination of membrane surface pore structure by atomic force microscopy, in P.Aimar and P.Aptel (Eds.), Recent Progres en Genie des Precedes // Membrane preparation Fouling - Emerging processes. CPIC, Nancy. 1992. V. 6, p. 5964. 29. Bottino A., Capannelli G., Grosso A., Monticelli O., Cavalleri O., Rolandi R., Soria R. Surface characterization of ceramic membranes by atomic force microscopy // J. Membr. Sci. 1994. V. 95, p. 289296. 30. Bowen W.R., Hall N.J. Properties of microfiltration membranes: mechanisms of flux loss in the recovery of an enzyme // Biotechnol. and Bioeng. 1995. V. 46, p. 2835. 31. Bowen W.R., Hilal N., Lovitt R.W., Williams P.M. Atomic force microscope studies of membranes: Surface pore structures of Cyclopore and Anopore membranes // J. Membr. Sci. 1996. V. 110, p. 233238. 32. Bowen W.R., Filippov A.N., Sharif A.O., Starov V.M. A model of the interaction between a charged particle and a pore in a charged membrane surface // Adv. Colloid and Interface Sci. 1999. V. 81, No. 1, p. 3572. 33. .. - : .... .. . 02.00.11 . ., 1999, 300 .

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