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Moscow University Chemistry Bulletin Vol. 52, No. 3, P. 175 (2011)
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V. A. Durov, A. P. Moscalets

Method of recursive sequences in associated liquids theory

Abstract

A new method based on recursive sequences (RS) is developed to calculate differential and integral characteristics of supramolecular organization, as well as dielectric properties of associated liquids in the framework of quasi-chemical model of non-ideal associated solution (QCNAS). In case of chain association the comparison of RS-method with earlier developed matrix technique is performed. The RS-method is consistent with matrix-based technique in detailed description of structure and properties of aggregates, and moreover can be extended to models of branched (for instance, tree-like) supramolecular structure of liquids.
Moscow University Chemistry Bulletin.
2011, Vol. 52, No. 3, P. 175
   

Copyright (C) Chemistry Dept., Moscow State University, 2002
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