Äîêóìåíò âçÿò èç êýøà ïîèñêîâîé ìàøèíû. Àäðåñ îðèãèíàëüíîãî äîêóìåíòà : http://www.mgumus.chem.msu.ru/publication/14-annex.pdf Äàòà èçìåíåíèÿ: Sat Jan 4 16:32:34 2003 Äàòà èíäåêñèðîâàíèÿ: Mon Oct 1 19:48:37 2012 Êîäèðîâêà:

319

IJBEH@?GBY
Ijbeh`_gb_ 3.1 I_j\bqgu_^Zggu_ihwe_f_glghfmkhklZ\mij_iZjZlh\ ]mfmkh\uodbkehlCHN bO ­^Zggu_we_f_glgh]hZgZebaZlhjZ Sbahevghklv­jmqgh_kh``_gb_H2O ­ihh[jZlghfmgZ[hjm\_kZ Ij_iZjZl C PHF-T10L94 PHF-T10L98 PHF-T1H94 PHF-T3L98 PHF-T4H94 PHF-T4H98 PHF-T5H94 PHF-T5H98 PHF-T6H94 PHF-T6H98 PHF-T7H94 PHF-T7H98 PHF-TH94 PHF-TMu4H PHF-TTL94 PHF-TTL98 PHA-T10L98 PHA-T3L98 PHA-T4H98 PHA-T5H98 PHA-T6H98 PHA-T7H98 PHA-TH8 PHA-THTO 3G$-TSkL00 PHA-TTL98 48.9 37.6 48.5 53.8 48.2 53.3 48.2 48.4 48.1 49.3 47.6 47.3 50.1 49.7 48.9 48.8 49.9 52.0 47.8 48.4 49.4 52.1 52.4 46.4 47.5 50.1 H 4.5 3.6 5.1 4.8 5.0 4.7 4.9 4.8 4.8 4.6 4.8 4.3 4.5 5.0 4.3 4.0 5.0 4.6 4.5 4.6 4.6 4.7 5.2 4.6 4.2 4.4 Kh^_j`Zgb_fZkk N 2.1 2.2 1.9 1.8 2.3 3.3 2.1 1.8 1.2 1.2 1.4 1.0 1.6 1.9 2.4 1.8 2.0 2.3 2.0 2.1 1.5 1.3 1.7 2.5 2.5 2.1 O =NDlhjnZ 27.5* 36.2 36.8* 33.1* 36.3* 35.9 34.2 35.7* 34.8 1.4 2.8 1.1 2.4 1.0 1.9 2.8 1.4 2.9 1.6 0.8 22.5 4.7 4.7 1.5 1.1 3.0 1.5 3.3 1.4 2.0 8.9 1.4 0.0 2.1 3.8 0.0 2.4 4.5 4.4 0.5 0.0 4.7 12.3 11.3 2.0 S Ash H 2O

7.2 7.9 7.4 9.2 9.2 8.8 8.3

=DlhjnZ

29.9*

10.1


320 Ij_iZjZl C PFA-T10L98 PFA-T3L98 PFA-T4H98 PFA-T5H98 PFA-T6H98 PFA-T7H98 PFA-TSkL00 PFA-TTL98 PDOM-TH PDOM-TT SHF-Co94 SHF-CtK98 SHF-CtV98 SHF-Gw98 SHF-PMu9 SHF-TMu12 SHA-Cm94 SHA-Cm98 SHA-CtK98 SHA-CtV94 SHA-Gp94 SHA-Gw94 SHA-Pg94 SHA-Pg96 SHA-Pp94 SHA-Pp96 SHA-Pw94 SHA-Pw96 SHA-Pw98 SHA-PwN SHA-K1 47.1 46.7 49.3 44.7 45.2 46.1 38.1 46.9 42.2 43.8 41.0 44.4 34.4 39.4 32.5 45.5 51.9 55.1 41.9 49.9 40.1 45.4 39.0 44.7 41.5 38.0 43.3 45.3 48.9 52.2 28.0 H 4.0 3.9 4.4 4.7 4.8 4.7 3.7 3.8 5.3 5.5 4.6 3.3 3.0 4.0 3.9 4.8 3.7 3.4 2.8 3.4 4.4 4.5 4.1 4.4 4.7 4.4 4.2 5.1 5.2 4.9 3.0 Kh^_j`Zgb_fZkk N O S NDlhjnZ 1.2 0.5 0.5 1.9 0.5 0.7 1.6 1.1 JH
Ash 1.8 0.0 0.0 0.8 11.1 3.6 11.2 1.4 1.1 2.6 16.0 2.8 21.0 15.7 27.6 5.9 7.0 1.2 27.0 7.4 9.0 10.1 22.2 11.3 9.1 21.6 11.7 10.0 7.8 1.7 32.3

H 2O

11.0

7.2

11.0

11.1 11.6 9.8 9.4 11.2 11.3

7.1


321 Ij_iZjZl C SFA-Cm94 SFA-Cm98 SFA-Ct94 SFA-Gp94 SFA-Gw94 SFA-Pg94 SFA-Pg96 SFA-Pp94 SFA-Pp96 SFA-Pw94 SFA-Pw96 SFA-Pw98 SDHF-Pg96 SDHF-Pp96 SDHF-Pw96 CHA-AGK CHA-ALD CHA-RO CHA-K2 CHA-K3 CHA-K4 AHF- RI AHFRMX2/8 AHF- RMX8 AHF- RND3 AHF-MMu7 AHF-MMu8 AHF-RMC AHF-RMX2 AHF-RND14 43.5 47.5 44.7 38.2 43.9 41.4 43.8 41.2 45.5 38.2 43.9 45.8 30.6 22.0 13.5 49.0 43.1 49.3 50.0 41.2 29.9 48.5 41.0 45.0 32.4 18.8 37.5 42.1 32.3 14.2 H 4.4 4.2 4.0 4.2 4.7 4.2 4.1 4.5 4.4 3.8 4.3 4.1 3.6 3.0 2.2 4.1 3.8 4.1 2.4 2.5 2.8 5.1 4.2 4.5 3.7 2.6 4.0 4.9 3.3 2.2 Kh^_j`Zgb_fZkk N 3.1 2.5 3.3 3.0 3.4 2.8 2.6 3.9 4.7 1.7 3.0 1.4 0.3 0.1 0.1 =Dm]e_c 0.5 0.7 1.1 0.4 1.2 0.5 1.0 1.3 1.2 1.4 0.3 0.5 2.4 0.7 0.1 38.2* 1.8 16.6 27.0 9.5 19.3 26.7 39.8 3.6 14.4 11.0 29.8 48.0 18.0 4.8 31.8 57.6 6.3 6.3 10.3 O NDihq\ 36.8 39.8 38.8 40.3 41.0 40.1 39.2 11.2 12.3 8.9 16.5 7.7 11.0 5.7 11.1 4.5 17.7 7.1 2.2 30.8 46.7 60.4 10.9 8.4 9.8 9.0 S Ash H 2O

8.4

=NDihq\_ggh]hjZkl\hjZ

=NDijbjh^guo\h^ 1.8 1.0 2.7 3.0 1.3 3.2 5.3 1.2

28.6


322 Ij_iZjZl C ADOM-SMu4 ADOM-SMu8 ADOM-SSh1 BHF-RLuh BHF-RND13 BHF-SMu2 BHA-SSk00 BHA-SSk00 35.2 30.5 26.9 25.9 45.3 45.7 48.6 39.9 H 3.8 3.8 2.9 3.3 5.1 4.6 5.4 3.5 Kh^_j`Zgb_fZkk N 0.5 2.2 0.1 1.9 1.9 2.0 3.3 ND^hgguohleh`_gbc 2.4 7.3 O S 0.9 1.2 1.3 Ash 19.6 31.0 42.1 35.0 4.0 6.0 7.5 H 2O 11.1 9.6 JH
=ND^hgguohleh`_gbc 5.2 3.1

=D^hgguohleh`_gbc

* ­ih^ZggufB

323 Ijbeh`_gb_ >Zggu_ihwe_f_glghfmkhklZ\mij_iZjZlh\]mfmkh\uodbkehl bkijZ\e_ggu_gZahevghklvb\eZ`ghklvbZlhfgu_hlghr_gby kh^_j`Zgb_O jZkkqblZghihjZaghklbkh^_j`Zgb_H2O 8%) Ij_iZjZl C PHF-T10L94 PHF-T10L98 PHF-T1H94 PHF-T3L98 PHF-T4H94 PHF-T4H98 PHF-T5H94 PHF-T5H98 PHF-T6H94 PHF-T6H98 PHF-T7H94 PHF-T7H98 PHF-TH94 PHF-TMu4H PHF-TTL94 PHF-TTL98 PHA-T10L98 PHA-T3L98 PHA-T4H98 PHA-T5H98 PHA-T6H98 PHA-T7H98 PHA-TH8 PHA-THTO 3G$-TSkL00 PHA-TTL98 53.6 54.2 55.5 61.5 52.8 58.6 54.1 53.5 53.9 54.3 53.6 56.9 56.0 54.5 54.6 55.3 54.3 58.0 54.6 55.2 54.0 56.7 60.0 59.8 58.9 55.6 H 3.9 3.8 4.8 4.5 4.6 4.2 4.5 4.3 4.4 4.1 4.3 4.1 3.9 4.4 3.7 3.5 4.4 4.2 4.2 4.3 4.1 4.1 4.9 4.5 4.2 3.9 N 2.3 3.2 2.2 2.0 2.5 3.6 2.4 2.0 1.3 1.3 1.6 1.3 1.8 2.0 2.7 2.1 2.2 2.6 2.3 2.4 1.7 1.4 2.0 3.2 3.1 2.3 Kh^_j`Zgb_fZkk O 38.7 37.8 34.3 31.0 38.9 30.9 37.8 39.2 38.2 39.2 37.4 36.8 36.8 35.9 37.3 38.1 38.1 34.2 37.9 37.1 39.3 36.8 32.1 31.6 32.9 37.2 S 1.6 1.0 3.2 1.0 1.2 2.7 1.1 1.0 2.1 1.0 3.1 1.0 1.5 3.1 1.7 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 H/C 0.88 0.85 1.03 0.87 1.02 0.86 1.00 0.97 0.96 0.91 0.99 0.87 0.87 1.00 0.83 0.76 0.98 0.87 0.92 0.93 0.91 0.87 0.99 0.96 0.85 0.83 O/C 0.54 0.52 0.46 0.38 0.54 0.40 0.52 0.55 0.52 0.54 0.54 0.48 0.51 0.50 0.52 0.52 0.53 0.44 0.52 0.50 0.55 0.49 0.40 0.43 0.42 0.50 C/N 28 20 30 35 25 20 27 31 47 49 39 53 36 31 24 31 29 26 28 27 38 46 36 22 22 28 =NDlhjnZ

=DlhjnZ


324 Ij_iZjZl C PFA-T10L98 PFA-T3L98 PFA-T4H98 PFA-T5H98 PFA-T6H98 PFA-T7H98 PFA-TSkL00 PFA-TTL98 PDOM-TH PDOM-TT SHF-Co94 SHF-CtK98 SHF-CtV98 SHF-Gw98 SHF-PMu9 SHF-TMu12 SHA-Cm94 SHA-Cm98 SHA-CtK98 SHA-CtV94 SHA-Gp94 SHA-Gw94 SHA-Pg94 SHA-Pg96 SHA-Pp94 SHA-Pp96 SHA-Pw94 SHA-Pw96 SHA-Pw98 SHA-PwN SHA-K1 52.2 50.8 53.6 49.0 55.9 52.1 47.1 51.7 48.0 49.0 53.4 49.7 48.4 51.6 50.4 52.8 63.3 60.7 64.4 61.2 50.5 56.7 56.9 55.3 52.1 54.0 56.3 55.2 58.1 57.2 47.0 H 3.4 3.2 3.9 4.2 4.8 4.3 3.4 3.2 4.7 5.2 5.0 2.7 3.0 4.1 4.7 4.5 3.0 2.7 3.0 2.7 4.0 4.3 4.5 4.3 4.3 5.0 3.9 5.1 5.1 4.5 3.6 Kh^_j`Zgb_fZkk N O S H/C NDlhjnZ 1.3 42.1 1.0 0.78 0.5 44.5 1.0 0.76 0.5 41.0 1.0 0.86 2.0 43.8 1.0 1.02 0.6 37.6 1.0 1.03 0.8 41.7 1.0 1.00 2.0 46.4 1.0 0.88 1.2 42.9 1.0 0.74 JH
O/C 0.60 0.66 0.57 0.67 0.50 0.60 0.74 0.62 1.18 1.27 0.39 0.66 0.70 0.57 0.57 0.49 0.34 0.39 0.33 0.42 0.63 0.43 0.45 0.48 0.60 0.48 0.46 0.46 0.40 0.41 0.92

C/N 48 120 127 28 101 75 27 49 29 52 15 20 23 15 24 19 14 16 25 16 12 12 14 16 13 11 12 14 15 17 14


325 Ij_iZjZl C SFA-Cm94 SFA-Cm98 SFA-Ct94 SFA-Gp94 SFA-Gw94 SFA-Pg94 SFA-Pg96 SFA-Pp94 SFA-Pp96 SFA-Pw94 SFA-Pw96 SFA-Pw98 SDHF-Pg96 SDHF-Pp96 SDHF-Pw96 CHA-AGK CHA-ALD CHA-RO CHA-K2 CHA-K3 CHA-K4 AHF- RI AHF-RMX2/8 AHF- RMX8 AHF- RND3 AHF-MMu7 AHF-MMu8 AHF-RMC AHF-RMX2 AHF-RND14 55.9 59.6 54.0 50.6 53.2 51.8 50.8 50.9 52.0 51.7 51.7 51.0 49.9 48.5 42.9 67.0 66.4 59.8 68.8 63.0 57.2 54.9 52.8 54.3 50.7 42.7 50.7 48.3 53.6 41.4 H 4.0 4.2 3.7 4.4 4.3 4.0 3.7 4.5 4.0 3.9 4.0 3.6 4.4 4.6 4.1 4.1 4.5 3.9 2.0 2.5 3.7 4.7 4.3 4.5 4.7 4.0 4.2 4.6 4.0 3.7 N 4.0 3.2 4.0 3.9 4.1 3.4 3.0 4.8 5.4 2.2 3.5 1.5 0.4 0.2 0.3 0.7 1.0 1.3 0.5 1.8 1.0 1.1 1.6 1.5 2.2 0.7 0.7 2.7 1.1 0.3 Kh^_j`Zgb_fZkk O 35.1 32.1 37.3 40.0 37.3 39.7 41.4 38.8 37.7 41.2 39.7 42.9 44.3 45.6 51.7 25.8 27.1 34.1 27.7 31.7 37.1 37.2 40.1 36.4 37.7 49.7 40.1 38.3 39.3 53.7 S 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 2.5 1.0 1.0 1.0 1.0 1.0 2.0 1.3 3.3 4.7 3.0 4.3 6.0 2.0 1.0 H/C 0.87 0.85 0.81 1.05 0.98 0.92 0.88 1.06 0.91 0.90 0.94 0.84 0.67 0.71 0.90 0.79 0.81 0.78 0.35 0.48 0.77 1.04 0.97 0.95 1.05 1.12 1.00 1.15 0.88 1.07 O/C 0.47 0.40 0.52 0.59 0.53 0.58 0.61 0.57 0.54 0.60 0.58 0.63 1.06 1.14 1.15 0.32 0.31 0.43 0.30 0.38 0.49 0.51 0.57 0.48 0.52 0.87 0.59 0.59 0.55 0.97 C/N 16 22 16 15 15 18 19 12 11 27 17 40 146 283 167 112 77 55 167 41 69 57 38 43 26 74 83 21 55 166 NDihq\

=NDihq\_ggh]hjZkl\hjZ

=Dm]e_c

=NDijbjh^guo\h^


326 Ij_iZjZl C ADOM-SMu4 ADOM-SMu8 ADOM-SSh1 BHF-RLuh BHF-RND13 BHF-SMu2 BHA-SSk00 BFA-SSk00 50.8 51.3 53.8 45.5 51.5 53.1 57.5 47.1 H 3.7 4.6 4.0 4.3 4.8 4.3 5.3 3.1 N 0.7 3.6 0.2 3.4 2.1 2.3 3.8 2.9 Kh^_j`Zgb_fZkk O 43.4 38.5 40.9 45.8 35.7 36.7 32.3 45.9 S 1.3 2.0 1.0 1.0 5.9 3.7 1.0 1.0 H/C 0.64 0.56 0.57 0.75 0.52 0.52 0.42 0.73 O/C 0.87 1.08 0.89 1.13 1.12 0.97 1.1 0.79 C/N 85 17 314 16 28 27 17 19 JH
=ND=DbND^hgguohleh`_gbc


327 Ijbeh`_gb_ Bgl_]jZevgu_bgl_gkb\ghklb^bZiZahgh\ KYFJki_dljh\ ij_iZjZlh\ijbjZaebqguo\j_f_gZoj_eZdkZpbhgghcaZ^_j`db
13

Ij_iZjZl

Ki_dljZevgZyh[eZklvf^ 220-185 185-167 167-145 145-108 I
1

108-90 2.5 2.4 4.7 2.6 2.3 3.9 5.1 3 1.2 1.9 2.2 0 1 2.9 3.1 1.4 2.5 0 2.7 1.9 3.2 2.8 3 3.8 4.2 2.9

90-50 17.3 19.3 28.7 22.3 26.5 21.9 22 25.4 25 25.7 26.9 9.1 20 19.8 19.6 17.3 22.2 7.5 15.4 13.5 16.7 18.8 16.5 16.3 16.2 19

50-5 21.6 24.7 22.2 28.4 20 18.2 22.5 18.9 28.6 23.7 23.5 28.6 15.4 19.1 25.4 21 23.1 23.5 18.2 20.5 18.1 24.7 15.8 15.6 19.2 16.9

SHF-Pw94 SHF-PwN PHF-T1094 PHF-T594 PHF-T694 PHF-T794 PHF-TT94 PHF-TH94 SFA-Pw94 SFA-Pg94 AHF-RI CHA-ALD PHF-T694 PHF-TH94 SFA-Pw94 SFA-Pg94 AHF-RI CHA-ALD SHF-Pw94 SHF-PwN PHF-T1094 PHF-T594 PHF-T694 PHF-T794 PHF-TT94 PHF-TH94

0.7 1.8 1.4 1.5 1.2 1.9 1.1 1.6 2.6 2.9 1.2 2.1 1.5 1.3 2.2 2.8 2.5 1.1 0.9 2.1 1.5 1.7 1.5 1.8 1.2 1.8

13.1 9.3 8.3 9.4 8.8 10.7 9.4 10.6 11.6 11.3 11.6 9.2 11.1 14.4 16.2 16 14.5 11.9 16.8 14.3 14.2 14.5 13.3 14.6 14.3 14.4

12.6 10.4 8 12.8 10.3 12.2 10.7 11.4 8.9 9.5 9.3 10 I 12.9 12.8 10.6 11.6 11.3 12.7 I 13 14 14.3 13.7 13.9 14.6 13.9 15.5
3 2

32.2 32.1 26.6 23.1 31 31.2 29.1 29 22 24.9 25.3 40.9 38.2 29.6 22.9 29.9 23.9 43.2 33 33.7 32 23.8 36 33.3 31 29.5


328 Ij_iZjZl Ki_dljZevgZyh[eZklvf^ 220-185 185-167 167-145 145-108 I SHF-Pw94 SHF-PwN PHF-T594 PHF-T694 PHF-T794 PHF-T1094 PHF-TT94 PHF-TH94 SFA-Pw94 SFA-Pg94 AHF-RI CHA-ALD PHF-T694 PHF-TH94 SFA-Pw94 SFA-Pg94 AHF-RI CHA-ALD 0.9 1 1.3 2.3 4.7 2.1 1.5 0.7 2.7 3 2 1 3.1 1.2 2 2.2 1.2 0.9 17.1 14.2 12.1 13.4 15.1 16.1 13.7 15.3 19.6 18 18 15 13.9 15 20 18.3 17.5 15.1 12.5 14 16 14.2 15.8 15.4 15.4 14.5 12 12 12 13 I 13.5 14.3 12.3 13.1 13.4 13
8 4

108-90 2.1 3.3 1.2 0.9 2.4 1.3 5 2.7 2 2 3 0 0.6 2.1 2.7 2 3.6 0

90-50 16.5 13.3 22.1 17.5 14.2 15.7 16.1 17.7 17 17 19 7 17.2 17.5 17.5 16.9 18.6 7.1

50-5 18.6 20.3 22.7 14.2 14.8 16.4 18.1 20.2 23.7 19 20 21 14.2 21.2 22.1 19.1 19.9 20.5

32.4 33.9 24.6 37.5 33.1 33.1 30.1 28.9 23 29 26 43 37.5 28.7 23.4 28.4 25.8 43.4


329 Ijbeh`_gb_ HibkZl_evgu_klZlbklbdb KYFJ-^ZgguoihjZkij_^_e_gbxK\ kljmdlmj_]mfmkh\uodbkehlkh^_j`Zgb_K\khklZ\_njZ]f_glh\ ^Zgh\hlh[s_]hK
13

NjZ]f_gl C=O COO CArO CAr OCO CHO CH2O CH3O &Gn CAr CCarb C=O COO CArO CAr OCO CHO CH2O CH3O &Gn CAr CCarb C=O COO CArO CAr OCO CHO CH2O

X

Med X 2.4 15.3 12.7 29.4 3.5 11.0 2.6 3.1 17.4 45.5 19.3

min

3.0 14.8 12.2 30.0 3.8 12.8 2.8 3.1 17.5 42.2 19.4

0.5 10.8 6.9 24.8 0.5 7.5 1.3 1.7 13.8 33.4 11.4

Xmax =ND 7.3 17.3 17.3 38.3 6.9 22.7 5.5 4.5 20.9 49.5 31.5

Q25 Q75 s2 A lhjnZQ  2.0 4.7 3.1 1.09 13.4 16.6 3.8 ­0.73 8.6 15.3 12.2 ­0.04 25.9 33.2 18.0 0.47 2.9 5.6 3.8 0.10 9.0 16.2 20.0 0.87 2.1 3.3 1.1 1.19 2.4 3.7 0.7 0.12 16.1 19.1 3.5 0.03 35.4 46.9 37.1 ­0.46 14.5 26.1 37.5 0.57 1.5 9.3 28.2 15.8 1.3 14.2 0.6 1.4 19.3 65.5 26.8 0.15 ­0.51 1.29 ­0.82 0.63 ­1.42 ­1.20 1.27 ­0.46 1.01 ­1.17

E 1.07 ­0.26 ­1.36 ­0.88 ­0.67 ­0.05 1.63 ­0.84 ­0.15 ­1.78 ­0.74 ­2.21 ­0.37 0.28 2.13 ­0.78 1.61 2.00 3.02 ­0.72 1.62 0.81 ­1.75 0.81 0.63 3.32 1.81 ­1.87 3.08

W 0.895 0.924 0.941 0.933 0.962 0.913 0.916 0.971 0.973 0.816 0.935 0.875 0.976 0.801 0.905 0.932 0.839 0.895 0.887 0.938 0.925 0.880 0.954 0.890 0.980 0.846 0.947 0.751 0.832

=D 3.0 2.6 1.6 4.5 13.6 14.1 8.6 17.5 11.1 9.2 6.7 20.6 32.4 32.2 25.0 37.9 2.5 2.3 1.1 4.3 10.9 12.3 3.7 14.2 2.5 2.7 1.0 3.4 4.1 4.0 2.6 6.5 19.8 20.5 13.3 25.7 43.5 42.0 33.1 58.6 16.0 17.6 6.4 20.7

lhjnZQ  1.7 4.1 11.0 16.1 7.2 16.5 31.7 35.4 1.7 3.7 8.2 14.1 2.2 3.3 3.4 4.4 14.8 22.7 38.8 48.6 12.4 20.1 lhjnZQ  1.6 3.5 10.9 15.2 6.9 8.8 24.0 25.1 5.4 6.9 12.7 26.1 2.3 3.5

ND 2.6 2.6 1.1 3.9 13.1 12.0 9.8 18.9 7.8 7.6 4.9 10.9 24.9 24.4 21.6 30.2 6.3 6.0 3.7 9.6 21.1 24.4 12.3 26.6 3.3 3.0 2.2 5.6

1.2 ­0.12 11.3 1.20 4.1 0.26 8.1 1.41 3.8 0.79 45.0 ­0.89 1.6 1.67


330 NjZ]f_gl CH3O &Gn CAr CCarb C=O COO CArO CAr OCO CHO CH2O CH3O &Gn CAr CCarb C=O COO CArO CAr OCO CHO CH2O CH3O &Gn CAr CCarb C=O COO CArO CAr OCO CHO CH2O Med 2.5 2.3 18.6 19.9 32.7 32.2 30.6 35.6
X

Xmin 1.2 11.9 26.5 18.8

Xmax Q25 Q75 s2 A 4.1 1.8 3.2 1.1 0.53 24.9 13.2 21.6 26.1 ­0.31 38.9 31.3 34.9 16.8 0.07 37.2 20.5 36.1 73.1 ­0.96 ihq\Q  1.5 2.2 12.9 16.8 7.4 13.1 31.9 35.8 3.0 4.0 10.5 11.0 2.6 3.0 3.2 4.0 14.2 26.1 40.3 45.0 16.7 18.7  2.8 17.4 12.4 37.9 3.0 10.3 2.7 5.4 21.9 50.2 15.9 1.3 13.5 16.3 32.3 3.6 8.3 0.5 5.8 53.5 21.7 18.0 0.7 2.4 4.0 56.2 0.6 4.8 0.5 0.9 17.2 63.7 9.9 1.16 ­0.82 0.06 0.26 1.98 ­2.03 ­0.25 0.54 0.26 ­0.11 ­1.66 0.41 0.57 ­0.50 0.54 0.75 ­0.65 ­0.21 0.13 0.21 ­0.01 ­0.29

E ­0.39 ­1.58 1.12 ­1.77 1.88 0.07 ­2.01 0.78 3.90 4.35 1.25 1.89 ­2.47 ­0.43 3.16 0.02 ­0.95 ­0.69 ­0.19 ­0.82 0.40 0.16 ­0.17 ­0.96 ­0.92 ­0.13 1.32 2.15 ­0.03 0.52 1.98 3.06 1.28

W 0.973 0.924 0.963 0.727 0.925 0.955 0.921 0.979 0.690 0.725 0.972 0.938 0.920 0.985 0.844 0.952 0.899 0.924 0.949 0.790 0.947 0.956 0.979 0.963 0.961 0.966 0.962 0.915 0.910 0.981 0.814 0.779 0.976

=ND 2.0 1.7 0.8 3.8 14.5 15.4 9.0 18.4 9.4 8.2 4.4 14.0 33.6 32.6 26.2 41.7 4.1 3.0 3.0 7.4 9.9 11.0 4.8 12.0 2.7 2.7 1.7 3.7 3.8 3.6 0.7 7.4 20.0 18.7 12.1 28.9 43.1 44.0 36.9 49.1 16.7 18.0 9.5 20.5 2.2 16.3 10.6 33.6 2.7 9.0 2.2 4.7 18.7 44.2 13.9 2.1 15.6 11.0 32.5 2.5 9.7 2.1 4.8 18.3 44.7 14.0 1.0 14.3 7.0 21.0 2.0 4.0 0.8 3.0 12.6 31.0 7.6 =D 4.0 19.0 13.0 48.1 4.1 12.2 3.5 6.6 26.0 56.8 19.0

ihq\Q 1.7 15.0 9.4 29.3 2.0 8.0 2.0 4.0 15.5 37.7 12.0

ND 3.1 3.3 2.0 4.0 20.1 19.7 18.0 23.0 9.4 8.7 7.0 13.1 24.1 24.5 19.0 28.2 2.3 2.2 2.0 3.0 11.5 10.5 9.9 15.0 2.5 2.5 2.0 3.0

ihq\Q  2.6 3.7 0.7 ­0.83 18.8 21.4 4.4 1.14 7.3 11.5 7.6 1.04 21.3 26.9 15.0 ­0.62 2.0 2.7 0.2 1.52 10.0 13.0 5.8 1.76 2.2 2.8 0.2 0.36


331 NjZ]f_gl CH3O &Gn CAr CCarb C=O COO CArO CAr OCO CHO CH2O CH3O &Gn CAr CCarb C=O COO CArO CAr OCO CHO CH2O CH3O &Gn CAr
X

Med X

min

X

max

Q

25

Q

75

s2

A

E 0.71 0.21 1.52 3.46 ­2.68 ­2.13 ­1.63 ­0.15 1.21 4.29 ­3.33 1.36 ­2.68 ­0.95 4.22 2.087 0.538 ­0.162 0.357 1.065 1.339 1.704 0.384 0.168 0.495

W 0.979 0.852 0.948 0.761 0.831 0.916 0.851 0.965 0.762 0.703 0.684 0.953 0.865 0.847 0.681 ­ ­ ­ ­ ­ ­ ­ ­ ­ ­

4.1 4.1 3.5 4.5 3.8 4.4 0.2 ­0.65 22.5 23.6 17.6 25.1 19.8 25.1 12.6 ­1.15 33.4 33.2 26.0 41.3 29.6 37.3 39.1 0.22 16.3 15.0 14.2 21.0 14.4 18.2 10.2 =Dm]e_cQ  2.0 16.3 15.8 45.9 1.4 1.8 0.6 2.7 13.3 61.8 3.8 2.6 15.4 11.1 32.0 3.3 11.1 2.4 3.7 18.4 43.1 2.7 16.6 17.9 47.8 0.0 1.1 1.0 2.7 10.8 57.8 1.2 0.5 15.0 10.0 38.0 0.0 0.0 0.1 0.2 5.2 56.0 1.0 3.1 17.7 19.3 52.8 4.8 6.9 1.0 6.0 21.0 71.9 12.7 1.0 15.2 13.0 43.0 0.0 0.0 0.1 1.6 8.9 57.3 1.0 2.9 16.9 19.0 48.0 2.1 1.1 1.0 3.0 20.8 65.9 3.3 1.4 1.3 17.1 31.6 4.5 8.4 0.2 4.6 51.7 47.2 25.5 1.6 7.7 14.1 55.6 3.8 33.3 1.1 2.0 21.9 90.4 ­0.64 ­0.06 ­0.83 ­0.42 1.43 2.04 ­0.61 0.80 0.25 0.98 2.05 1.046 ­0.258 0.636 0.826 0.884 0.780 0.452 0.075 ­0.206 0.657 1.85

H[t_^bg_ggZy\u[hjdZQ  2.4 0.5 7.3 1.7 3.2 15.4 8.6 23.0 14.2 17.0 10.3 4.4 20.6 8.1 13.1 31.8 19.0 52.8 25.9 35.3 3.0 0.0 9.6 2.0 4.1 10.5 0.0 26.6 8.0 12.5 2.5 0.1 5.6 2.0 3.0 3.8 0.2 7.4 2.7 4.5 18.3 5.2 28.9 15.9 21.6 42.8 26.0 71.9 34.9 48.0

­ CCarb 16.8 15.6 1.0 37.2 12.5 20.1 63.8 0.612 1.070 , Xmin, Xmaxb0HG­kj_^gb_fbgbfZdkagZq_gbybf_^bZgZ; Q25b475 ­gb`gb_b\_jogb_d\Zjlbeb : b ?­ dhwnnbpb_glu Zkbff_ljbb b wdkp_kkZ : ­ agZq_gb_ djbl_jby MbedZ-RZibjh @bjgufrjbnlhf\u^_e_gu: < (W0.05)djbl.


332 Ijbeh`_gb_ HibkZl_evgu_klZlbklbdbIFJ-^ZgguoihjZkij_^_e_gbxG \kljmdlmj_]mfmkh\uodbkehlkh^_j`Zgb_G\khklZ\_njZ]f_glh\ ^Zgh\hlh[s_]hG NjZ]f_gl COOH ArOH ArH AlkOH CHO AlkH HAr HCarb COOH ArOH ArH AlkOH CHO AlkH HAr HCarb COOH ArOH ArH AlkOH CHO AlkH HAr HCarb COOH ArOH ArH AlkOH
X

Med X

min

8.8 8.1 13.2 8.5 32.6 29.2 0.2 0.4 7.3 10.9 14.8 4.3 32.1 31.0 0.2 0.4 8.9 5.7 12.0 8.6 36.6 27.4 0.2 0.5 7.8 7.7 13.7 8.7

9.0 6.0 9.0 3.0 13.0 9.0 9.0 2.0 32.0 29.0 29.0 22.0 0.2 0.1 0.4 0.4 7.0 6.0 10.5 6.0 14.5 12.0 3.5 0.0 32.5 24.0 31.0 29.0 0.2 0.2 0.4 0.3 9.0 6.0 6.0 2.0 12.0 8.0 8.0 3.0 37.0 29.0 27.0 16.0 0.2 0.1 0.5 0.4 8.0 4.0 8.0 5.0 13.0 10.0 6.5 4.0

Xmax Q25 Q75 =NDlhjnZQ  10.0 8.0 10.0 13.0 8.0 9.0 20.0 10.0 16.0 15.0 9.0 9.0 38.0 30.0 35.0 38.0 28.0 31.0 0.2 0.2 0.2 0.5 0.4 0.5 =DlhjnZQ  11.0 6.0 7.5 17.0 9.0 12.5 18.0 13.0 16.5 9.0 2.5 6.5 38.0 29.5 35.5 35.0 29.5 31.5 0.2 0.2 0.2 0.5 0.4 0.4 NDlhjnZQ  11.0 7.0 10.0 9.0 4.0 7.0 16.0 11.0 13.0 16.0 5.0 11.0 43.0 33.0 41.0 38.0 23.0 34.0 0.2 0.1 0.2 0.6 0.4 0.6 =Dihq\Q  11.0 7.0 9.0 9.0 7.0 9.0 20.0 12.0 14.0 21.0 5.0 9.0

s2 1.7 7.2 11.1 9.9 9.1 13.1 0.002 0.001 2.8 11.6 4.8 9.1 21.0 3.7 0.001 0.001 3.1 5.2 5.7 19.6 22.6 56.3 0.001 0.006

A -0.84 -0.46 0.38 -0.47 0.31 0.62 0.03 0.43 1.94 0.58 0.10 0.48 -0.63 1.28 0.29 -0.91 -0.71 -0.33 0.00 0.54 -0.28 -0.09 -0.80 -0.31

E -0.02 0.40 -0.17 2.31 -1.32 3.18 -0.79 -0.95 4.18 0.59 -1.09 -0.47 -0.11 2.31 -0.98 0.82 -0.53 0.06 2.07 -0.20 -0.34 -0.64 0.46 -1.43

W 0.831 0.909 0.914 0.757 0.906 0.898 0.977 0.934 0.753 0.954 0.943 0.946 0.960 0.869 0.931 0.904 0.919 0.981 0.923 0.958 0.986 0.977 0.918 0.945 0.955 0.821 0.866 0.747

5.4 -0.57 1.50 2.7 -0.86 -0.30 11.9 1.44 2.72 39.5 2.06 4.47


333 NjZ]f_gl CHO AlkH HAr HCarb COOH ArOH ArH AlkOH CHO AlkH HAr HCarb COOH ArOH ArH AlkOH CHO AlkH
X

Med X

min

X

max

Q

25

Q

75

s2

A

E

W 0.977 0.917 0.753 0.809 0.897 0.915 0.925 0.863 0.978 0.867 0.853 0.974 -

26.8 27.0 22.0 32.0 24.0 29.0 35.2 35.5 31.0 39.0 32.0 38.0 0.2 0.4 10.0 4.8 9.4 8.2 29.8 37.8 0.1 0.4 8.5 7.7 12.9 7.6 32.0 31.3 0.2 0.4 0.2 0.3 0.3 0.4 0.2 0.4 0.2 0.4

12.6 0.08 -0.29 11.0 -0.17 -2.20 0.002 1.99 0.001 -1.81 4.09 3.55

NDihq\Q  10.0 5.0 13.0 9.0 13.0 4.0 2.0 8.0 3.0 7.0 10.0 4.0 13.0 9.0 11.0 8.0 6.0 11.0 8.0 8.0 29.0 24.0 36.0 27.0 33.0 39.0 34.0 42.0 34.0 40.0 0.1 0.4 0.1 0.3 0.2 0.5 0.1 0.4 0.1 0.4 11.0 -0.82 0.14 6.7 0.36 -2.41 11.3 -1.17 2.03 3.2 0.82 2.36 22.7 0.21 -1.27 13.2 -0.20 -2.59 0.002 -1.43 3.01 0.002 0.41 -0.96 4.2 0.10 -0.09 10.3 0.41 0.80 10.6 -0.03 0.71 16.5 0.91 2.23 23.2 0.03 -0.28 28.8 -0.33 0.70

H[t_^bg_ggZy\u[hjdZQ  9.0 4.0 13.0 7.0 10.0 8.0 2.0 17.0 5.0 9.0 13.0 4.0 20.0 11.0 15.0 8.0 0.0 21.0 5.0 9.0 32.0 22.0 43.0 29.0 35.0 31.0 16.0 42.0 29.0 34.0

HAr 0.2 0.2 0.1 0.3 0.2 0.2 0.002 -0.21 1.52 HCarb 0.4 0.4 0.3 0.6 0.4 0.5 0.004 0.59 0.37 X , Xmin, Xmaxb0HG­kj_^gb_fbgbfZdkagZq_gbybf_^bZgZ Q25b475 ­gb`gb_b\_jogb_d\Zjlbeb : b ?- dhwnnbpb_glu Zkbff_ljbb b wdkp_kkZ : - agZq_gb_ djbl_jby MbedZ-RZibjh @bjgufrjbnlhf\u^_e_gu: < (W0.05)djbl.


334

Rbnj

SHA-Pw94 SHA-PwN

SHA-Cmg

SFA-Pw94 SFA-Pg94

PHF-T594 PHF-T694 PHF-T794 PHF-T1094 PHF-TH94 PHF-TT94 PHA-THTO

AHF- RMX8 AHF- RI AFA-GFg1 AFA-SHo10

Ijbeh`_gb_ NjZ]f_glguckhklZ\ij_iZjZlh\]mfmkh\uodbkehljZaebqgh]hijhbkoh`^_gbybnjZdpbhggh]hkhklZ\Z CO COOH COOR CAr-OH CAr-OR CAr-H CAr-C CH3O CH-OH CH2OH CAlk H/CAlk H/CAr H/CAlk-O =D^_jgh\h-ih^ahebkluoihq\ 1.0 9.0 8.0 7.0 5.0 13.4 18.6 3.0 14.3 2.7 18.0 1.88 0.30 1.37 2.0 8.2 6.8 7.1 5.9 12.3 17.7 4.5 12.9 2.6 20.0 1.94 0.29 1.48 =Dq_jgha_fZ 2.0 9.6 5.4 7.4 3.1 17.5 28.0 3.0 7.5 1.5 15.0 1.87 0.27 1.60 ND^_jgh\h-ih^ahebkluoihq\ 3.0 13.0 7.0 7.5 4.5 8.5 13.5 3.0 13.5 2.5 24.0 1.62 0.25 1.26 3.0 14.2 3.8 8.4 3.6 10.0 19.0 3.5 13.0 2.5 19.0 1.88 0.26 1.49 =ND lhjnZ 1.0 8.4 7.6 5.3 4.7 10.5 17.5 3.0 16.0 3.0 23.0 1.74 0.29 1.44 2.0 8.9 5.1 9.4 4.6 14.6 23.4 3.0 12.5 2.5 14.0 1.82 0.26 1.52 2.0 9.6 7.4 8.7 6.3 15.4 18.6 4.0 11.0 2.0 15.0 1.67 0.30 1.70 2.0 8.9 7.1 10.4 4.6 13.4 19.6 4.0 11.5 2.5 16.0 1.79 0.28 1.65 2.0 7.9 7.1 7.9 6.1 12.9 18.1 4.0 14.0 3.0 17.0 1.74 0.28 1.51 3.0 8.6 6.4 8.6 4.4 12.4 19.6 3.5 13.5 3.0 17.0 1.75 0.26 1.41 3.0 7.3 5.7 8.4 4.6 12.6 18.4 5.0 15.8 3.2 16.0 1.96 0.30 1.48 =NDijbjh^guo\h^ 2.0 13.5 5.5 5.6 5.4 7.9 17.1 5.0 10.0 4.0 24.0 1.87 0.25 1.65 3.0 14.2 3.8 9.1 2.9 8.5 17.5 5.5 8.5 4.0 23.0 1.78 0.26 1.83 1.0 12.6 3.4 4.6 4.4 7.4 17.6 3.0 15.5 4.5 26.0 1.82 0.25 1.39 1.0 11.0 7.0 9.0 4.0 11.0 19.0 3.0 13.5 4.0 17.5 1.78 0.26 1.42


335

Rbnj 21.0 21.0 14.0 15.0 13.0 1.92 2.03 1.91 1.94 1.88 0.35 0.35 0.30 0.25 0.28

CO

CAlk H/CAlk H/CAr H/CAlk-O 3.04 2.79 1.53 1.84 1.29

CHA-AGK CHA-ALD

1.0 1.0

SHF-Co94 SDFA-BS1 PHF-TMu4

1.0 3.0 2.0

COOH COOR CAr-OH CAr-OR CAr-H CAr-C CH3O CH-OH CH2OH =Dm]ey 13.1 2.9 6.1 3.9 21.5 26.5 4.0 0.0 0.0 12.0 3.5 8.5 4.0 19.5 23.5 6.0 0.0 1.0 >jm]h_ 10.8 7.2 7.2 5.8 12.9 19.1 4.0 15.0 3.0 14.7 2.3 8.6 2.4 12.2 25.8 5.5 8.5 2.0 10.8 6.2 8.6 3.4 9.7 16.3 2.0 22.0 6.0


336 Ijbeh`_gb_

1

H,1H COSYki_dlj=Dgbabggh]hlhjnZPHA-T10L98.

1

H,1H COSYki_dlj]b^jhebam_fhcqZklb(PHHD-T10L98).


337

1

H,13C+64&ki_dlj=Dgbabggh]hlhjnZPHA-T10L98.

1

H,13C+64&ki_dlj]b^jhebam_fhcqZklb(PHHD-T10L98).


338

1

H,1H COSYki_dlj=D\_joh\h]hlhjnZPHA-T7H98.

1

H,1H COSYki_dlj]b^jhebam_fhcqZklb(PHHD-T7H98).


339

1

H,13C+64&ki_dlj=D\_joh\h]hlhjnZPHA-T7H98.

1

H,13C+64&ki_dlj]b^jhebam_fhcqZklb(PHHD-T7H98).


340 Ijbeh`_gb_ <_ebqbgZg_wdkdexabhggh]hwnn_dlZKd)^eybg^b\b^mZevguo hj]Zgbq_kdbokh_^bg_gbc\\u[jZgghc ojhfZlh]jZnbq_kdhckbkl_f_ No 1 ;jmllhnhjfmeZ C7H6O4 Kh_^bg_gb_ K
d

No

2

3 4

5

6

7 8 9 10 11 12

3,4>b]b^jhdb[_gahcgZy dbkehlZ C7H6O4 3,5>b]b^jhdb[_gahcgZy dbkehlZ C9H10O5 Kbj_g_\Zy dbkehlZ C7H6O5 3,4,5Ljb]b^jhdcb[_gahcgZy dbkehlZ C7H6O3 3=b^jhdb[_gahcgZy dbkehlZ C7H6O3 4=b^jhdb[_gahcgZy dbkehlZ C9H10O2 =b^jhdhjbqgZydbkehlZ C9H11O2N N_gbeZeZgbg C4H8O
2

-2.21 33

;jmllhKh_^bg_gb_ Kd nhjfmeZ C7H12O6 ObggZydbkehlZ 0.23

-2.21 34

C4H6O

2

Djhlhgh\Zy dbkehlZ

0.23

-0.41 35 -2.55 36

C4H6O

2

C6H10O

7

F_lZdjbeh\Zy 0.23 dbkehlZ =exdmjhgh\Zy 0.24 dbkehlZ FZkeygZy dbkehlZ

-0.74 37

C4H8O

2

0.25

-0.74 38

C9H8O

4

DZj[hdkbn_gbe 0.27 -mdkmkgZyd-lZ

-0.31 39 -0.29 40

1,4->bhdkZg -0.19 41 :p_lhg ;_gahcgZy dbkehlZ WlZghe F_lbhgbg -0.15 42 -0.14 43 -0.08 44 -0.05 45

C3H6O C7H6O
2

C2H6O

13 C5H11O2NS

2-DZj[hdkbdhjbqgZydbkehlZ C10H10O4 ;_gabefZehgh\ZydbkehlZ C10H10O4 1,2-N_gbe_g^bmdkmkgZyd-lZ C3H6O3 FhehqgZy dbkehlZ C5H9O4N =emlZfbgh\Zy dbkehlZ C4H7O4N :kiZj]bgh\Zy dbkehlZ C4H4O4 FZe_bgh\Zy dbkehlZ C10H8O
4

0.27 0.28 0.28 0.29 0.30 0.31 0.32


341 14 15 C8H8O
2

C18H16O

5

16 17 18 19 20 21

C18H16O

5

C6H13O2N C6H12O C3H8O CH4O C9H8O
4 6

N_gbemdkmkgZydbkehlZ 4-[4-(2DZj[hdkb[_gahbe)N_gbe[mlZgh -\ZydbkehlZ E_cpbg =exdhaZ =ebp_jbg F_lZghe

-0.04 46 -0.04 47

C8H6O C8H6O

4

4

NlZe_\Zy dbkehlZ L_j_nlZe_\Zy dbkehlZ :djbeh\Zy dbkehlZ =ebhdkZe_\Zy dbkehlZ Ijhibhgh\Zy dbkehlZ =ebdhe_\Zy dbkehlZ MdkmkgZy dbkehlZ =emdZjh\Zy dbkehlZ FmjZ\vbgZy dbkehlZ :^bibgh\Zy dbkehlZ Ibf_ebgh\Zy dbkehlZ =emlZjh\Zy dbkehlZ =emlZdhgh\Zy dbkehlZ
0.32 0.32

-0.04 48 -0.03 49 -0.01 50 0.00 0.02 51 52 53

C3H4O C2H2O C3H6O C2H4O C2H4O

2

0.32 0.33 0.34 0.33 0.35 0.35

3

2

3

3

2

:p_lbekZebp 0.03 beh\Zy dbkehlZ 0.04 22 C8H8O3 2F_lhdkb[_gahcgZy dbkehlZ 23 C5H11ONS 2

C6H10O

8

54

CH2O

2

0.38

55 56 57 58 59 60 61 62 63 64

C6H10O C7H12O C5H8O C5H6O C4H6O C6H8O C4H6O C4H6O C3H4O C2H2O

4

0.40 0.41 0.41 0.41 0.42 0.42 0.42 0.43 0.44 0.47

25 C6H12O4N S2 26 C5H9O2N 27 28 29 30 31 32 C4H9NO3 C3H7O3N C3H7O2N C2H5O2N C5H10O C5H10O
2

2

=_dkZgh\Zy dbkehlZ Pbklbg Ijhebg Lj_hgbg K_jbg :eZgbg =ebpbg

0.05 0.07 0.07 0.09 0.11 0.12 0.15

4

4

4

6 7

5

4

2

Bah\Ze_jbZgh 0.20 -\ZydbkehlZ
4

4


342 Ijbeh`_gb_


343


344


345


346


347 Ijbeh`_gb_


348


349


350


351


352 Ijbeh`_gb_ Kibkhdbg^b\b^mZevguokh_^bg_gbcbkihevah\Zgguo^eyjZkq_lZ ¨ihklhygghcyq_cdb´bkhhl\_lkl\mxsb_*)expijbgf Kh_^bg_gb_ ;_gahekmevnhgh\Zy 3-n_gbeijhibhgh\Zy 5-]b^jhdkbn_gbemdkmkgZy 4-]b^jhdkbn_gbemdkmkgZy 3-]b^jhdkb[_gahcgZy 2-f_lhdkb[_gahcgZy NlZe_\Zyoj NlZe_\Zyoj 2,3-]b^jhdkb[_gahcgZy 3,5-]b^jhdkb[_gahcgZy H[ Sijbgf ,MN,&
hj]

Bgl_]jZeojihMN/ bgl_]jZeojihKhj] 0.0514 0.0427 0.0763 0.0526 0.0855 0.0967 0.162 0.162 0.316 0.318 1.068 1.278

(*)expijbgf 0.0048 0.0061 0.0083 0.0097 0.0111 0.0117 0.0186 0.0186 0.0297 0.0326 0.0872 0.1005

H[ Sijbgf â,MN,& 5


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exp


353 Ijbeh`_gb_
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