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... Chem. 12, 357363 (1999) Imine exchange in O-aryl and O-alkyl oximes as a base reaction for aqueous `dynamic' combinatorial libraries. ... The basic reaction that can be used for reversible exchange of building blocks Y in O-substituted oximes is depicted in Scheme 1. ... The above results, combined with the kinetics of the imine exchange, support the proposal that the formation of the hydrated oxime 9 is rate limiting in both imine exchange with aryloxymine and the hydrolysis reactions. ...
... These processes are both mediated by eukaryotic initiation factor 4F (eIF4F), which consists of eIF4A (helicase), eIF4E (cap-binding protein), and eIF4G subunits. ... We have recently found that the initiation mediated by the IRES of encephalomyocarditis virus (EMCV) has the same requirements (45). eIF4A exhibits RNA-dependent ATPase activity and, in conjunction with eIF4B, RNA helicase activity (29, 49). ... 16, 1996 FUNCTIONAL DOMAINS OF eIF4G 6871 FIG. ... UV cross-linking of EMCV RNA. ... FIG. ...